Enhancement of mechanical properties in 3D-printed Zr-based bulk metallic glass composites via multiscale heterogeneous structures

The inescapable precipitation of brittle intermetallics in 3D-printed bulk metallic glasses (BMGs) significantly deteriorates their plasticity. To solve this problem, a novel scanning strategy (alternating high and low laser energy density between layers) was developed to regulate B2-CuZr distribution in the 3D-printed Zr47.5Cu45.5Al5Co2 alloy, producing a multiscale heterostructure. The coupling effect of B2-CuZr phase transformation and multiscale heterostructure promotes the formation of massive shear bands while suppressing their unstable propagation, significantly enhancing the strength-plasticity synergy with ∼1.2 GPa yield strength, ∼1.9 GPa fracture strength and ∼7% plastic strain. This work offers a novel avenue to fabricate high-performance BMG composites.

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Publication Details

Journal
Materials Research Letters
Published
2026-01-07
DOI
https://doi.org/10.1080/21663831.2025.2611735
Primary Topic
Metallic Glasses and Amorphous Alloys
Type
article
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article

Enhancement of mechanical properties in 3D-printed Zr-based bulk metallic glass composites via multiscale heterogeneous structures

Lin Yuan, P Zhang, Jie Pan, Cheng Zhang et al.
Materials Research Letters
Metallic Glasses and Amorphous Alloys
article

Enhancement of mechanical properties in 3D-printed Zr-based bulk metallic glass composites via multiscale heterogeneous structures

Lin Yuan, P Zhang, Jie Pan, Cheng Zhang, Lin Liu, Di Ouyang, Huaping Ding
article en

Abstract

The inescapable precipitation of brittle intermetallics in 3D-printed bulk metallic glasses (BMGs) significantly deteriorates their plasticity. To solve this problem, a novel scanning strategy (alternating high and low laser energy density between layers) was developed to regulate B2-CuZr distribution in the 3D-printed Zr47.5Cu45.5Al5Co2 alloy, producing a multiscale heterostructure. The coupling effect of B2-CuZr phase transformation and multiscale heterostructure promotes the formation of massive shear bands while suppressing their unstable propagation, significantly enhancing the strength-plasticity synergy with ∼1.2 GPa yield strength, ∼1.9 GPa fracture strength and ∼7% plastic strain. This work offers a novel avenue to fabricate high-performance BMG composites.

Materials Research LettersVol. 14(2)
Southwest University (CN), Wuhan University of Technology (CN), Songshan Lake Materials Laboratory (CN), Huazhong University of Science and Technology (CN)
Affordable and clean energy
Openalex Percentile: Top 94%
Metallic Glasses and Amorphous Alloys
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Enhancement of mechanical properties in 3D-printed Zr-based bulk metallic glass composites via multiscale heterogeneous structures — Lin Yuan, P Zhang, et al. · Materials Research Letters (2026) | TGRS Research Map | TGRS