Patina Formation and Corrosion Processes in <i>Sefidruy</i> Beta Bronze Artifacts From the Rasht Archaeology Museum, Iran

ABSTRACT High‐tin bronze artifacts, known as Sefidruy vessels and preserved in the Rasht Archaeology Museum, Iran, were examined to investigate patina formation and corrosion processes. Dating mainly to the Sasanian period (224–651 ce ) and originating from Gilan province, these objects reflect a distinct copper–tin alloying tradition. Elemental analyses confirmed 20wt%–22 wt% tin with minor lead, whereas metallography revealed α and β (martensitic) phases characteristic of β bronze. X‐ray diffraction identified cuprite, malachite, and cassiterite, formed through selective phase corrosion. Results demonstrate the relationship between alloy composition, microstructure, and patina development, offering insights into technological practices and artifact preservation.

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Publication Details

Journal
Archaeometry
Published
2026-01-07
DOI
https://doi.org/10.1111/arcm.70087
Primary Topic
Metallurgy and Cultural Artifacts
Type
article
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article

Patina Formation and Corrosion Processes in Sefidruy Beta Bronze Artifacts From the Rasht Archaeology Museum, Iran

Hamidreza Bakhshandehfard, Omid Oudbashi, Soraya Mohammadi
Archaeometry
Metallurgy and Cultural Artifacts
article

Patina Formation and Corrosion Processes in Sefidruy Beta Bronze Artifacts From the Rasht Archaeology Museum, Iran

Hamidreza Bakhshandehfard, Omid Oudbashi, Soraya Mohammadi
article en

Abstract

ABSTRACT High‐tin bronze artifacts, known as Sefidruy vessels and preserved in the Rasht Archaeology Museum, Iran, were examined to investigate patina formation and corrosion processes. Dating mainly to the Sasanian period (224–651 ce ) and originating from Gilan province, these objects reflect a distinct copper–tin alloying tradition. Elemental analyses confirmed 20wt%–22 wt% tin with minor lead, whereas metallography revealed α and β (martensitic) phases characteristic of β bronze. X‐ray diffraction identified cuprite, malachite, and cassiterite, formed through selective phase corrosion. Results demonstrate the relationship between alloy composition, microstructure, and patina development, offering insights into technological practices and artifact preservation.

Archaeometry
Isfahan University of Art (IR), University of Gothenburg (SE)
Sustainable cities and communities
Openalex Percentile: Top 97%
Metallurgy and Cultural Artifacts
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