Oxygen‐Rich Zn‐Vitamin C Framework Enabling Specific Host‐Guest Recognition for Selective Hydrocarbon Separation and Dual‐Mode Fruit Preservation

Tailored host-guest interactions are essential for developing multifunctional adsorbents, yet integrating distinct adsorption roles into a single robust framework remains rare. Herein, we represent a green, biocompatible Zn-based metal-organic framework (ZnVc) constructed from edible-grade vitamin C ligands. The resulting oxygen-decorated pores deliver strong, selective guest binding through multiple hydrogen-bonding interactions. ZnVc exhibits inverse hydrocarbon selectivity with high affinity for C₂H₂ and C₂H₆ over C₂H₄, enabling one-step C₂H₄ purification from ternary C2 mixtures under ambient conditions. Theoretical modeling and in situ spectroscopy reveal that synergistic hydrogen-bonding and electrostatic interactions govern this selectivity. Beyond hydrocarbon separation, the oxygen-rich sites impart dual functionality in real fruit storage: efficient C₂H₄ scavenging couple with humidity regulation, markedly prolongs postharvest freshness. This work exemplifies how rational coordination chemistry and sustainable ligand choice can unite industrial and agricultural functions within a single adsorbent platform.