Empirical formula for specific heat of solids based on atomic constants and a universal subzero limiting temperature

We present a novel empirical approach to understand the specific heat capacities of solids by introducing a characteristic subzero reference temperature derived from fundamental atomic constants. Using the total energy of the electron associated with the Bohr radius and the proton- electron mass ratio, we define a universal lower temperature limit as 3.87862×10⁻¹⁴ K. Based on this temperature and a room temperature of 300 K, we propose a simple empirical relation for specific heat capacity expressed in terms of atomic mass number A: C = 25416.852/A J/kg.K. The formula accurately predicts experimental specific heat capacities across various elemental solids, providing a fundamental link between atomic-scale constants and macroscopic thermodynamic behaviour. Considering ‘grams to kilograms’ and ‘moles to kilomoles’ and with reference to Dulong-Petit law, it can be expressed as, C = [3 x 1000 x R]/A . It needs further study.

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Publication Details

Journal
EPJ Web of Conferences
Published
2026-01-01
DOI
https://doi.org/10.1051/epjconf/202634501029
Primary Topic
Chemical Thermodynamics and Molecular Structure
Type
article
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article

Empirical formula for specific heat of solids based on atomic constants and a universal subzero limiting temperature

Lakshminarayana S, Gunavardhana Naudu T, Seshavatharam U V S
EPJ Web of Conferences
Chemical Thermodynamics and Molecular Structure
article

Empirical formula for specific heat of solids based on atomic constants and a universal subzero limiting temperature

Lakshminarayana S, Gunavardhana Naudu T, Seshavatharam U V S
article en

Abstract

We present a novel empirical approach to understand the specific heat capacities of solids by introducing a characteristic subzero reference temperature derived from fundamental atomic constants. Using the total energy of the electron associated with the Bohr radius and the proton- electron mass ratio, we define a universal lower temperature limit as 3.87862×10⁻¹⁴ K. Based on this temperature and a room temperature of 300 K, we propose a simple empirical relation for specific heat capacity expressed in terms of atomic mass number A: C = 25416.852/A J/kg.K. The formula accurately predicts experimental specific heat capacities across various elemental solids, providing a fundamental link between atomic-scale constants and macroscopic thermodynamic behaviour. Considering ‘grams to kilograms’ and ‘moles to kilomoles’ and with reference to Dulong-Petit law, it can be expressed as, C = [3 x 1000 x R]/A . It needs further study.

EPJ Web of ConferencesVol. 345
Andhra University (IN), Chongqing Academy of Science and Technology (CN), Servier (France) (FR), Aditya Birla (India) (IN)
Affordable and clean energy
Openalex Percentile: Top 95%
Chemical Thermodynamics and Molecular Structure
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Empirical formula for specific heat of solids based on atomic constants and a universal subzero limiting temperature — Lakshminarayana S, Gunavardhana Naudu T, et al. · EPJ Web of Conferences (2026) | TGRS Research Map | TGRS