A tetranuclear lanthanum–nickel hydrido complex supported by an arene-anchored bis(phosphinomethylamido) ligand

Tetranuclear La(III)-Ni(0) iodide and hydride complexes featuring a Ni(0)→La(III) dative bond were synthesized and characterized using NMR spectroscopy, X-ray diffraction and computational analysis. The hydrido complex showed insertion reactivity with carbodiimide and isonitrile, while its reaction with <i>p</i>-tolunitrile led to a cyanide complex <i>via</i> C-N bond cleavage.

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Publication Details

Journal
Chemical Communications
Published
2026-01-01
DOI
https://doi.org/10.1039/d5cc06726j
Primary Topic
Organometallic Complex Synthesis and Catalysis
Type
article
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article

A tetranuclear lanthanum–nickel hydrido complex supported by an arene-anchored bis(phosphinomethylamido) ligand

Huayi Fang, Chih‐Yu Wu, Dongjing Hong, Xiuyan He et al.
Chemical Communications
Organometallic Complex Synthesis and Catalysis
article

A tetranuclear lanthanum–nickel hydrido complex supported by an arene-anchored bis(phosphinomethylamido) ligand

Huayi Fang, Chih‐Yu Wu, Dongjing Hong, Xiuyan He, Peng Cui
article en

Abstract

Tetranuclear La(III)-Ni(0) iodide and hydride complexes featuring a Ni(0)→La(III) dative bond were synthesized and characterized using NMR spectroscopy, X-ray diffraction and computational analysis. The hydrido complex showed insertion reactivity with carbodiimide and isonitrile, while its reaction with <i>p</i>-tolunitrile led to a cyanide complex <i>via</i> C-N bond cleavage.

Chemical CommunicationsVol. 62(12)
Nankai University (CN), Anhui Normal University (CN)
Openalex Percentile: Top 96%
Organometallic Complex Synthesis and Catalysis
DOISourceOpenAlex
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