Development of the CO2-Resistant Gel by Designing a Novel CO2-Responsive Polymer for Channel Control in Low-Permeability Reservoirs

To address the problem of serious gas channeling during CO₂ flooding in low-permeability reservoirs, which leads to poor oil recovery, this study developed a CO₂-resistant gel using a novel CO₂-responsive polymer (ADA) for gas channel control. The ADA polymer was synthesized via free-radical copolymerization of acrylamide (AM), dimethylaminopropyl methacrylamide (DMAPMA), and 2-acrylamido-2-methylpropanesulfonic acid (AMPS), which introduced protonatable tertiary-amine groups and sulfonate moieties into the polymer backbone. Comprehensive characterizations confirmed the designed structure and adequate thermal stability of the ADA polymer. Rheological tests demonstrated that the ADA polymer solution exhibits significant CO₂-triggered viscosity enhancement and excellent shear resistance. When crosslinked with phenolic resin, the resulting ADA gel showed outstanding CO₂ tolerance under simulated reservoir conditions (110 °C, 10 MPa). After 600 s of CO₂ exposure, the ADA gel retained over 99% of its initial viscosity, whereas a conventional HPAM-based industrial gel degraded to 61% of its original viscosity. The CO₂-resistance mechanism involves protonation of tertiary amines to form quaternary ammonium salts, which electrostatically interact with sulfonate groups, creating a reinforced dual-crosslinked network that effectively protects the gel from H⁺ ion attack. Core flooding experiments confirmed its ability to enhance oil recovery by plugging high-permeability channels and diverting flow, achieving a final recovery of up to 48.5% in heterogeneous cores. This work provides a novel gel system for improving sweep efficiency and storage security during CO₂ flooding in low-permeability reservoirs.