Synthesis of 2-butenedioates viamulticomponent reaction of isoquinoline

Isoquinoline reacts smoothly with dimethyl acetylenedicarboxylate (DMAD) in the presence of amides to produce dimethyl (E)-2-[1-[aryl(alkyl)carbonylamino]-2(1H)-isoquinolinyl]-2-butenedioates. Also, quinoline reacts with DMAD in the presence of benzamide to produce dimethyl (E)-2-[1-[(phenylcarbonyl)amino]-2(1H)- quinolinyl]-2-butenedioate.

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Publication Details

Published
2025-03-28
DOI
https://doi.org/10.82361/iranjoc.2025.1202883
Primary Topic
Synthesis and Characterization of Pyrroles
Type
article
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article

Synthesis of 2-butenedioates viamulticomponent reaction of isoquinoline

IAU
Synthesis and Characterization of Pyrroles
article

Synthesis of 2-butenedioates viamulticomponent reaction of isoquinoline

IAU
article en

Abstract

Isoquinoline reacts smoothly with dimethyl acetylenedicarboxylate (DMAD) in the presence of amides to produce dimethyl (E)-2-[1-[aryl(alkyl)carbonylamino]-2(1H)-isoquinolinyl]-2-butenedioates. Also, quinoline reacts with DMAD in the presence of benzamide to produce dimethyl (E)-2-[1-[(phenylcarbonyl)amino]-2(1H)- quinolinyl]-2-butenedioate.

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Synthesis and Characterization of Pyrroles
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Synthesis of 2-butenedioates viamulticomponent reaction of isoquinoline — IAU · (2025) | TGRS Research Map | TGRS