Study on Influencing Factors and Mechanism of Activated MgO Carbonation Curing of Tidal Mudflat Sediments

Offshore wind farm construction faces significant geotechnical challenges posed by tidal mudflat sediments, including high moisture content, low bearing capacity, and high sensitivity to disturbance. Utilizing MgO—a material characterized by abundant raw materials, low embodied energy, and environmental compatibility—for the stabilization of such soft soils represents a promising and sustainable approach worthy of further investigation. This study elucidates the carbonation-induced stabilization mechanism of coastal mucky soil from Ningbo, Zhejiang Province, through systematic monitoring of reaction temperature and unconfined compressive strength (UCS) testing under varying levels of reactive MgO content, carbonation duration, and initial moisture content. Microstructural characterization was performed using X-ray diffraction (XRD), scanning electron microscopy (SEM) and mercury intrusion porosimetry (MIP) to reveal the evolution of mineralogical and pore structure features associated with carbonation. The results indicate that increasing MgO content leads to higher peak reaction temperatures and shorter time-to-peak values. However, the rate of reduction in time-to-peak diminishes beyond 20% MgO. A secondary temperature rise is commonly observed between 3–3.5 h of carbonation in most specimens. When the MgO content is below 30%, UCS peaks within 6–10 h, with the peak time decreasing as MgO content increases. When MgO exceeds 45%, strength deterioration occurs due to structural damage. The correlation between deformation modulus and UCS is found to be comparable to that of conventional cement-stabilized soils. Microstructural analysis reveals that, with increased MgO dosage and prolonged carbonation, carbonation products progressively fill voids and bind soil particles, resulting in reduced total porosity and a refinement of pore size distribution—evidenced by a leftward shift in the most probable pore diameter. Nevertheless, at excessively high MgO levels (e.g., 50%), crystallization pressure from rapid product formation may generate macro-pores, compromising soil fabric integrity. This study presents a low-carbon and efficient ground improvement approach for access road construction in tidal mudflat wind farm developments.