Investigating the electrical transport properties and electronic structure of <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>Zr</mml:mi> <mml:mn>2</mml:mn> </mml:msub> <mml:msub> <mml:mi>CuSb</mml:mi> <mml:mn>

The checkerboard lattice has been proposed to host topological flat bands as a result of destructive interference among its various electronic hopping terms. However, it has proven challenging to realize experimentally due to the difficulty of isolating this structure from any significant out-of-plane bonding while maintaining structural integrity. Here, single crystals of Zr2CuSb3, a potential candidate for the checkerboard lattice, were synthesized using the solution (self-flux) method, and their structure was confirmed via X-ray diffraction. Electrical transport measurements indicate metallic behavior with electron-dominated carriers. Angle-resolved photoemission spectroscopy reveals multiple electron pockets and significant kz broadening due to its large c-axis and low dispersion features in k z. Density functional theory calculations further disentangle the contributions from each high-symmetry plane, providing a comprehensive characterization of electronic behavior.

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Publication Details

Journal
Physical Review Materials
Published
2026-01-02
DOI
https://doi.org/10.1103/qrll-lplv
Primary Topic
Rare-earth and actinide compounds
Type
article
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Investigating the electrical transport properties and electronic structure of <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>Zr</mml:mi> <mml:mn>2</mml:mn> </mml:msub> <mml:msub> <mml:mi>CuSb</mml:mi> <mml:mn>

Shane Smolenski, Eli Rotenberg, Demet Usanmaz, Chris M. Jozwiak et al.
Physical Review Materials
Rare-earth and actinide compounds
article

Investigating the electrical transport properties and electronic structure of <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>Zr</mml:mi> <mml:mn>2</mml:mn> </mml:msub> <mml:msub> <mml:mi>CuSb</mml:mi> <mml:mn>

Shane Smolenski, Eli Rotenberg, Demet Usanmaz, Chris M. Jozwiak, Aaron Bostwick, Ruiqi Tang, Anonymous, Na Hyun Jo, Soumya S. Bhat, Carly Mistick
article en

Abstract

The checkerboard lattice has been proposed to host topological flat bands as a result of destructive interference among its various electronic hopping terms. However, it has proven challenging to realize experimentally due to the difficulty of isolating this structure from any significant out-of-plane bonding while maintaining structural integrity. Here, single crystals of Zr2CuSb3, a potential candidate for the checkerboard lattice, were synthesized using the solution (self-flux) method, and their structure was confirmed via X-ray diffraction. Electrical transport measurements indicate metallic behavior with electron-dominated carriers. Angle-resolved photoemission spectroscopy reveals multiple electron pockets and significant kz broadening due to its large c-axis and low dispersion features in k z. Density functional theory calculations further disentangle the contributions from each high-symmetry plane, providing a comprehensive characterization of electronic behavior.

Physical Review MaterialsVol. 10(2)
Lawrence Berkeley National Laboratory (US), University of Michigan (US), Kettering University (US)
Sustainable cities and communities
Openalex Percentile: Top 95%
Rare-earth and actinide compounds
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Investigating the electrical transport properties and electronic structure of <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>Zr</mml:mi> <mml:mn>2</mml:mn> </mml:msub> <mml:msub> <mml:mi>CuSb</mml:mi> <mml:mn> — Shane Smolenski, Eli Rotenberg, et al. · Physical Review Materials (2026) | TGRS Research Map | TGRS