Cavity-Mediated Radiative Energy Transfer Enables Stable, Low-Threshold Lasing in Hybrid Quantum Dot-Nanoplatelet Supraparticles

Colloidal semiconductor nanocrystals are promising building blocks for optoelectronics due to their solution processability, spectral tunability, and ability to self-assemble into complex architectures. However, their use in lasing application remains limited by high working thresholds, rapid nonradiative losses from Auger recombination, and sensitivity to environmental conditions. Here, we report hybrid microscale supraparticles composed of core/shell CdSe/ZnS quantum dots (QDs) and CdSe/Cd<sub><i>x</i></sub>Zn<sub>1-<i>x</i></sub>S nanoplatelets (NPLs), which overcome these limitations through efficient, cavity-mediated energy funneling and coupling. Broadband absorbing QDs rapidly transfer excitation to narrow emitting NPLs, enabling stable whispering gallery mode lasing with a low threshold of 0.35 mJ/cm<sup>2</sup>. These supraparticles retain optical performance after prolonged exposure to air, water, and continuous irradiation, offering practical advantages for optoelectronic devices and advanced pigment technologies. Ultimately, our approach provides a versatile, programmable platform for optical amplification and tunable emission control within colloidal photonic architectures.

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Publication Details

Journal
ACS Nano
Published
2026-01-02
DOI
https://doi.org/10.1021/acsnano.5c15222
Primary Topic
Quantum Dots Synthesis And Properties
Type
article
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article

Cavity-Mediated Radiative Energy Transfer Enables Stable, Low-Threshold Lasing in Hybrid Quantum Dot-Nanoplatelet Supraparticles

Emanuele Marino, Cherie R. Kagan, Gary Chen, Yun Chang Choi et al.
ACS Nano
Quantum Dots Synthesis And Properties
article

Cavity-Mediated Radiative Energy Transfer Enables Stable, Low-Threshold Lasing in Hybrid Quantum Dot-Nanoplatelet Supraparticles

Emanuele Marino, Cherie R. Kagan, Gary Chen, Yun Chang Choi, ClaireYejin Kang, Christopher B. Murray, Cristian Gonzalez, Jun Xu
article en

Abstract

Colloidal semiconductor nanocrystals are promising building blocks for optoelectronics due to their solution processability, spectral tunability, and ability to self-assemble into complex architectures. However, their use in lasing application remains limited by high working thresholds, rapid nonradiative losses from Auger recombination, and sensitivity to environmental conditions. Here, we report hybrid microscale supraparticles composed of core/shell CdSe/ZnS quantum dots (QDs) and CdSe/Cd<sub><i>x</i></sub>Zn<sub>1-<i>x</i></sub>S nanoplatelets (NPLs), which overcome these limitations through efficient, cavity-mediated energy funneling and coupling. Broadband absorbing QDs rapidly transfer excitation to narrow emitting NPLs, enabling stable whispering gallery mode lasing with a low threshold of 0.35 mJ/cm<sup>2</sup>. These supraparticles retain optical performance after prolonged exposure to air, water, and continuous irradiation, offering practical advantages for optoelectronic devices and advanced pigment technologies. Ultimately, our approach provides a versatile, programmable platform for optical amplification and tunable emission control within colloidal photonic architectures.

ACS NanoVol. 20(2)
Texas A&M University System (US), California University of Pennsylvania (US), Industriale Chimica (Italy) (IT)
Affordable and clean energy
Openalex Percentile: Top 99%
Quantum Dots Synthesis And Properties
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Cavity-Mediated Radiative Energy Transfer Enables Stable, Low-Threshold Lasing in Hybrid Quantum Dot-Nanoplatelet Supraparticles — Emanuele Marino, Cherie R. Kagan, et al. · ACS Nano (2026) | TGRS Research Map | TGRS