Low-Temperature Oxidation Behavior and Non-Isothermal Heat Release of Heavy Oil During Oxygen-Reduced Air Injection

Oxygen-reduced air injection technology has demonstrated considerable potential for developing heavy oil reservoirs. However, the low-temperature oxidation (LTO) behavior and non-isothermal heat release of heavy oil under oxygen-reduced conditions remain poorly understood. Accordingly, this study systematically investigated the oxygen consumption characteristics of heavy crude oil under two oxygen concentrations (8% and 10%) through isothermal static oxidation experiments. Additionally, scanning electron microscopy (SEM) and differential scanning calorimetry (DSC) were employed to analyze the microstructural evolution of rock cuttings and the exothermic characteristics of heavy oil before and after oxidation. The results indicated that as the oxygen concentration increased from 8% to 10%, the pressure drop during the LTO process rose from 1.73 to 2.04 MPa, and the oxygen consumption rate increased from 1.47 × 10−5 to 2.06 × 10−5 mol/(h·mL). This demonstrated that higher oxygen partial pressure promoted LTO reactions, thereby generating more abundant coke precursors for the subsequent high-temperature oxidation (HTO) stage. SEM analysis revealed that the microstructure of the rock cuttings after oxidation transitioned from an originally smooth, “acicular” morphology to a “flaky” structure characterized by extensive crack development, which significantly improved the connectivity of the pore-fracture system. DSC analysis further demonstrated that the mineral components in the rock cuttings played a dual role during the oxidation process: at the LTO stage, their heat capacity effect suppressed the exothermic behavior during oxidation; whereas at the HTO stage, their larger specific surface area and the catalytic effect of clay minerals enhanced the heat release from coke combustion. This study thus provided a theoretical foundation for developing heavy oil reservoirs through oxygen-reduced air injection.