High-resolution spectroscopy of the <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:mi>X</mml:mi> <mml:mtext>–</mml:mtext> <mml:mi>A</mml:mi> </mml:mrow> </mml:math> transition of the carbon monoxide dication <mml:math xmlns

We report rovibronic spectra of the A $^3Σ^+$($v'=0-2$) - X $^3Π_Ω(v=0)$ rovibronic transitions ($|Ω|=0, 1$ and 2) of the CO$^{2+}$ doubly-charged molecular ion. Spectra were recorded at high resolution ($\sim 5$~cm$^{-1}$) in a fast beam of CO$^{2+}$ molecules by detecting the Coulomb explosion of the molecules upon excitation to the A state. Measurements were guided by \textit{ab initio} calculations which then assisted the assignment of the observed spectral features. Our results resolve the spin-orbit splittings of the ground vibronic state X $^3Π_Ω(v=0)$, but not the rotational structure of the bands due to spectral congestion, and provide spectroscopic information on CO$^{2+}$ with unprecedented resolution. In doing so they expand our knowledge of this benchmark doubly charged molecular ion and expand the short list of doubly charged molecules studied at high resolution.

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Publication Details

Journal
Physical review. A/Physical review, A
Published
2025-12-30
DOI
https://doi.org/10.1103/x1f1-445d
Primary Topic
Atomic and Molecular Physics
Type
article
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High-resolution spectroscopy of the <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:mi>X</mml:mi> <mml:mtext>–</mml:mtext> <mml:mi>A</mml:mi> </mml:mrow> </mml:math> transition of the carbon monoxide dication <mml:math xmlns

Nathalie Vaeck, Matthieu Génévriez, Antoine Aerts, Anonymous et al.
Physical review. A/Physical review, A
Atomic and Molecular Physics
article

High-resolution spectroscopy of the <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:mi>X</mml:mi> <mml:mtext>–</mml:mtext> <mml:mi>A</mml:mi> </mml:mrow> </mml:math> transition of the carbon monoxide dication <mml:math xmlns

Nathalie Vaeck, Matthieu Génévriez, Antoine Aerts, Anonymous, X. Urbain
article en

Abstract

We report rovibronic spectra of the A $^3Σ^+$($v'=0-2$) - X $^3Π_Ω(v=0)$ rovibronic transitions ($|Ω|=0, 1$ and 2) of the CO$^{2+}$ doubly-charged molecular ion. Spectra were recorded at high resolution ($\sim 5$~cm$^{-1}$) in a fast beam of CO$^{2+}$ molecules by detecting the Coulomb explosion of the molecules upon excitation to the A state. Measurements were guided by \textit{ab initio} calculations which then assisted the assignment of the observed spectral features. Our results resolve the spin-orbit splittings of the ground vibronic state X $^3Π_Ω(v=0)$, but not the rotational structure of the bands due to spectral congestion, and provide spectroscopic information on CO$^{2+}$ with unprecedented resolution. In doing so they expand our knowledge of this benchmark doubly charged molecular ion and expand the short list of doubly charged molecules studied at high resolution.

Physical review. A/Physical review, AVol. 113(1)
Université Libre de Bruxelles (BE), UCLouvain (BE)
Openalex Percentile: Top 31%
Atomic and Molecular Physics
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