Utilization of dual catalysts for high-yield boron nitride nanotube synthesis via chemical vapor deposition

The direct synthesis of boron nitride nanotubes (BNNTs) via chemical vapor deposition (CVD) in high-temperature furnaces remains highly challenging due to difficulties in optimizing key experimental parameters such as synthesis temperature and catalyst composition. These challenges often result in uncontrolled growth behavior, adversely affecting the quality and yield of the BNNTs. In this study, colemanite was effectively utilized as a boron source for the high-yield synthesis of directionally aligned BNNTs. The synthesis was carried out using a CVD method that used a dual-catalyst system comprising Fe₂O₃ and MgO in conjunction with a silicon carbide template under high-temperature conditions. The resulting BNNTs were characterized using scanning electron microscopy and high-resolution transmission electron microscopy, as well as spectroscopic methods including Fourier-transform infrared spectroscopy, Raman spectroscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. This innovative CVD strategy offers a cost effective and efficient way to produce high-purity BNNTs from colemanite, significantly expanding their potential for various applications.