The crystal structure of potassium 1-(2,2″,4,4″,6,6″-hexamethyl-[1,1′:3′,1″-terphenyl]-2′-yl)-2,2-diisopropyldiphosphane-1-carbodithioate <i>n</i> -hexane solvate, C <sub>124</sub> H <sub>156</sub> K <sub>4</sub> P <sub>8</sub> S <sub>8</sub> , 2(C <

Abstract C 136 H 184 K 4 P 8 S 8 , triclinic, P <m:math xmlns:m="http://www.w3.org/1998/Math/MathML" overflow="scroll"> <m:mrow> <m:mover accent="true"> <m:mn>1</m:mn> <m:mo>̅</m:mo> </m:mover> </m:mrow> </m:math> $&amp;#x305;{1}$ (no. 2), a = 12.4391(7) Å, b = 17.2716(9) Å, c = 17.9250(9) Å, α = 72.076(2)°, β = 85.408(2)°, γ = 69.279(2)°, V = 3425.3(3) Å 3 , Z = 1, R gt ( F ) = 0.0446, wR ref ( F 2 ) = 0.1314, T = 123 K Figure 1: A view of (a) the asymmetric unit, (b) the coordination sphere of K1 and (c) the full tetramer (H-atoms and n -hexane omitted for clarity, ter (2,6-bis(2,4,6-trimethylphenyl)phenyl) and i Pr substituents are depicted as wireframes). .

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Journal
Zeitschrift für Kristallographie - New Crystal Structures
Published
2025-12-27
DOI
https://doi.org/10.1515/ncrs-2025-0439
Primary Topic
Organometallic Compounds Synthesis and Characterization
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article
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article

The crystal structure of potassium 1-(2,2″,4,4″,6,6″-hexamethyl-[1,1′:3′,1″-terphenyl]-2′-yl)-2,2-diisopropyldiphosphane-1-carbodithioate n -hexane solvate, C 124 H 156 K 4 P 8 S 8 , 2(C <

Karsten Paul Lüdtke, Lilian Sophie Szych, Axel Schulz
Zeitschrift für Kristallographie - New Crystal Structures
Organometallic Compounds Synthesis and Characterization
article

The crystal structure of potassium 1-(2,2″,4,4″,6,6″-hexamethyl-[1,1′:3′,1″-terphenyl]-2′-yl)-2,2-diisopropyldiphosphane-1-carbodithioate n -hexane solvate, C 124 H 156 K 4 P 8 S 8 , 2(C <

Karsten Paul Lüdtke, Lilian Sophie Szych, Axel Schulz
article en

Abstract

Abstract C 136 H 184 K 4 P 8 S 8 , triclinic, P <m:math xmlns:m="http://www.w3.org/1998/Math/MathML" overflow="scroll"> <m:mrow> <m:mover accent="true"> <m:mn>1</m:mn> <m:mo>̅</m:mo> </m:mover> </m:mrow> </m:math> $&amp;#x305;{1}$ (no. 2), a = 12.4391(7) Å, b = 17.2716(9) Å, c = 17.9250(9) Å, α = 72.076(2)°, β = 85.408(2)°, γ = 69.279(2)°, V = 3425.3(3) Å 3 , Z = 1, R gt ( F ) = 0.0446, wR ref ( F 2 ) = 0.1314, T = 123 K Figure 1: A view of (a) the asymmetric unit, (b) the coordination sphere of K1 and (c) the full tetramer (H-atoms and n -hexane omitted for clarity, ter (2,6-bis(2,4,6-trimethylphenyl)phenyl) and i Pr substituents are depicted as wireframes). .

Zeitschrift für Kristallographie - New Crystal StructuresVol. 241(2)
University of Münster (DE), Leibniz Institute for Catalysis (DE), University of Rostock (DE)
Openalex Percentile: Top 33%
Organometallic Compounds Synthesis and Characterization
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