Fluctuation–dissipation theorems in porous media two-phase flow: statistical characterisation of saturation fluctuations and measurement of Onsager coefficients

We introduce a novel experimental approach for measuring Onsager coefficients in steady-state multiphase flow through porous media, leveraging the fluctuation–dissipation theorem to analyse saturation fluctuations. This method provides a new tool for probing transport properties in porous media, which could aid in the characterisation of key macroscopic coefficients such as relative permeability. The experimental set-up consists of a steady-state flow system in which two incompressible fluids are simultaneously injected into a modified Hele-Shaw cell, allowing direct visualisation of the dynamics through optical imaging. By computing the temporal correlations of saturation fluctuations, we extract Onsager coefficients that govern the coupling between phase fluxes. Additionally, we have performed a statistical analysis of the fluctuations in the derivative of saturation under different flow conditions. This analysis reveals that while the fluctuations follow Gaussian statistics up to 2–3 standard deviations, they exhibit heavy tails beyond this range. This work provides an experimental foundation for recent theoretical developments in the extention of non-equilibrium thermodynamics to multiphase porous media flows. By linking microscopic fluctuations to macroscopic transport behaviour, our approach offers a new perspective that may complement existing techniques in the study of multiphase flow, making it relevant to both statistical physics and the broader fluid mechanics community.