Evaluating Coal Quality and Trace Elements of the Karagandy Coal Formation (Kazakhstan): Implications for Resource Utilization and Industry

The Carboniferous coal seams in Northeast Kazakhstan remain insufficiently investigated, with a lack of comprehensive mineralogical and geochemical assessments necessary to understand the geological processes controlling coal quality. This study examines 15 coal samples from the Karagandy Coal Formation (KCF) at the Saradyr and Bogatyr mines using proximate and ultimate analyses, FTIR, XRD, SEM–EDS, ED-XRF, and ICP-OES, providing the first detailed comparison of mineralogical and geochemical characteristics—including depositional signals and inorganic constituent distribution—between these mines within the KCF. The coals exhibit an average ash yield of 24.1% on a dry basis, volatile matter of 21.6% on a dry and ash-free basis, and low moisture content of 1.1% (air-dry), with low sulfur levels of 0.7% in whole coal across both mines. Mineralogical composition is dominated by quartz and clay minerals, with minor pyrite, apatite, chalcopyrite, and rutile. Major oxides in the coal ash average 68.2% SiO2 and 19.5% Al2O3, followed by Fe2O3, K2O, and TiO2 (3–12.1%). Among the 24 identified trace elements, Sm is the most abundant at 6.3 ppm with slight enrichment (CC = 2.8), Lu remains at normal levels (CC < 1), and most other elements are depleted (CC < 0.5). The Al2O3/TiO2 ratios (3.8–10.8) indicate contributions from intermediate to mafic parent materials. The detrital mineralogy, parting compositions, and elevated ash content indicate significant accommodation space development during or shortly after peat accumulation, likely within a vegetated alluvial plain depression. These findings provide new insights into the depositional environment and coal-forming processes of the KCF and contribute to regional assessments of coal quality and resource potential.

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Resources
Published
2025-12-25
DOI
https://doi.org/10.3390/resources15010005
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1
Primary Topic
Coal and Its By-products
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article
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1.34
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article

Evaluating Coal Quality and Trace Elements of the Karagandy Coal Formation (Kazakhstan): Implications for Resource Utilization and Industry

Geroy Zh. Zholtayev, Ahmed H. Moghazi, Zamzagul Umarbekova, Yerzhan Nurmakanov et al.
1 citations
Resources
Coal and Its By-products
1.34
article

Evaluating Coal Quality and Trace Elements of the Karagandy Coal Formation (Kazakhstan): Implications for Resource Utilization and Industry

Geroy Zh. Zholtayev, Ahmed H. Moghazi, Zamzagul Umarbekova, Yerzhan Nurmakanov, Moldir A. Mashrapova, Medet Junussov, Mohamed Abdelnaby Oraby, Kuanysh Togizov
article en
1 citations

Abstract

The Carboniferous coal seams in Northeast Kazakhstan remain insufficiently investigated, with a lack of comprehensive mineralogical and geochemical assessments necessary to understand the geological processes controlling coal quality. This study examines 15 coal samples from the Karagandy Coal Formation (KCF) at the Saradyr and Bogatyr mines using proximate and ultimate analyses, FTIR, XRD, SEM–EDS, ED-XRF, and ICP-OES, providing the first detailed comparison of mineralogical and geochemical characteristics—including depositional signals and inorganic constituent distribution—between these mines within the KCF. The coals exhibit an average ash yield of 24.1% on a dry basis, volatile matter of 21.6% on a dry and ash-free basis, and low moisture content of 1.1% (air-dry), with low sulfur levels of 0.7% in whole coal across both mines. Mineralogical composition is dominated by quartz and clay minerals, with minor pyrite, apatite, chalcopyrite, and rutile. Major oxides in the coal ash average 68.2% SiO2 and 19.5% Al2O3, followed by Fe2O3, K2O, and TiO2 (3–12.1%). Among the 24 identified trace elements, Sm is the most abundant at 6.3 ppm with slight enrichment (CC = 2.8), Lu remains at normal levels (CC < 1), and most other elements are depleted (CC < 0.5). The Al2O3/TiO2 ratios (3.8–10.8) indicate contributions from intermediate to mafic parent materials. The detrital mineralogy, parting compositions, and elevated ash content indicate significant accommodation space development during or shortly after peat accumulation, likely within a vegetated alluvial plain depression. These findings provide new insights into the depositional environment and coal-forming processes of the KCF and contribute to regional assessments of coal quality and resource potential.

ResourcesVol. 15(1)
Ain Shams University (EG), University of Iceland (IS), Satbayev University (KZ), Nazarbayev University (KZ)
Openalex Percentile: Top 14%
Coal and Its By-products
1.34
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