Multiscale Investigation into the Growth Kinetics of Strontium Nitrate Crystals Based on an Ultrasound–Visual Dual-Modal Monitoring System
To address limitations in real-time 3D morphology acquisition for crystal growth kinetics, this study pioneers an ultrasound–visual dual-modal monitoring system integrating stereoscopic imaging, ultrasonic attenuation, and molecular simulation. The system achieves 37% lower edge-length error in 3D reconstruction vs 2D projection and enables real-time concentration tracking via a PCA-GA-BP neural network (R2 = 0.9998). Kinetic experiments (n = 50) demonstrate that the (200) plane grows 14.5% faster than (111) (0.544 vs 0.475 μm/min) with higher temperature sensitivity (18% enhancement at 323.15 K). Molecular simulations reveal stronger water adsorption on (111) planes (−41.26 vs −10.84 kcal/mol), while the Modified Adsorption Energy (MAE) model corrects solvent-accessible area effects: the (111) plane proportion decreases from 67.14% to 47.44%, whereas (200) increases to 52.56%, aligning with experimental habits. This integrated methodology provides cross-scale insights for inorganic salt crystallization mechanisms and industrial process optimization.
Authors
- Zhuo Lei (ORCID: https://orcid.org/0000-0001-6042-6810)
- Bo Li (ORCID: https://orcid.org/0000-0002-7294-6888)
- Shuxuan Wang (ORCID: https://orcid.org/0000-0002-1870-5477)
- Qihang Zhu
- Xingwu Zou
- Fei Shao (ORCID: https://orcid.org/0000-0002-8742-9197)
- Xiaoqiang Li
- Chunlai Yang
Institutions
- Chinese Academy of Sciences (CN)
- Lanzhou University of Technology (CN)
- University of Chinese Academy of Sciences (CN)
Publication Details
- Journal
- Crystal Growth & Design
- Published
- 2025-12-25
- DOI
- https://doi.org/10.1021/acs.cgd.5c01492
- Primary Topic
- Crystallization and Solubility Studies
- Type
- article
- Field-Weighted Citation Impact
- 0.00