2-Methyl- <i>N</i> -[( <i>E</i> )-4-nitrobenzylidene]propan-2-amine

The title compound, C 11 H 14 N 2 O 2 , is a Schiff base derived from tert -butylamine and para -nitrobenzaldehyde. All atoms except the methyl groups are located on a mirror plane. Thus, there is only half a molecule in the asymmetric unit. The tert -butyl group shows rotational disorder over four positions. The molecule is E -configured. In the extended structure, C—H...O contacts connect the molecules into chains along [010] in the crystal structure.

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Publication Details

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IUCrData
Published
2025-12-18
DOI
https://doi.org/10.1107/s2414314625011368
Primary Topic
Crystal structures of chemical compounds
Type
article
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article

2-Methyl- N -[( E )-4-nitrobenzylidene]propan-2-amine

Eric C. Hosten, Richard Betz
IUCrData
Crystal structures of chemical compounds
article

2-Methyl- N -[( E )-4-nitrobenzylidene]propan-2-amine

Eric C. Hosten, Richard Betz
article en

Abstract

The title compound, C 11 H 14 N 2 O 2 , is a Schiff base derived from tert -butylamine and para -nitrobenzaldehyde. All atoms except the methyl groups are located on a mirror plane. Thus, there is only half a molecule in the asymmetric unit. The tert -butyl group shows rotational disorder over four positions. The molecule is E -configured. In the extended structure, C—H...O contacts connect the molecules into chains along [010] in the crystal structure.

IUCrDataVol. 10(12)
Nelson Mandela University (ZA)
Openalex Percentile: Top 44%
Crystal structures of chemical compounds
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2-Methyl- <i>N</i> -[( <i>E</i> )-4-nitrobenzylidene]propan-2-amine — Eric C. Hosten, Richard Betz · IUCrData (2025) | TGRS Research Map | TGRS