Crystal structure of poly[μ-diphenyl(pyridin-4-yl)phosphane-κ <sup>2</sup> <i>N</i> : <i>P</i> -μ-trifluoroacetato-κ <sup>2</sup> <i>O</i> : <i>O</i> ′-silver(I)] from synchrotron data
The crystal structure of the title compound, [Ag(CF<sub>3</sub>CO<sub>2</sub>)(C<sub>17</sub>H<sub>14</sub>NP)] has been determined from synchrotron data (λ = 0.70000 Å). Centrosymmetric dinuclear Ag<sub>2</sub>O<sub>2</sub> units, generated by inversion centers, extend into a two-dimensional coordination polymer linked by the N and P atoms of the bridged-bidentate (μ<sup>2</sup>) ligand. The resulting two-dimensional array can be described as a 6<sup>3</sup> (hcb) network.
Authors
- Young-A Lee
- Jiyeong Song
- Dongwon Kim
Institutions
- Pohang University of Science and Technology (KR)
- Pohang TechnoPark (South Korea) (KR)
- Jeonbuk National University (KR)
Publication Details
- Journal
- Acta Crystallographica Section E Crystallographic Communications
- Published
- 2025-12-18
- DOI
- https://doi.org/10.1107/s2056989025011302
- Primary Topic
- Organometallic Complex Synthesis and Catalysis
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Research Foundation
- Pohang University of Science and Technology
- Ministry of Science, ICT and Future Planning
- National Research Foundation of Korea
- Ministry of Science and ICT, South Korea