1-[( <i>E</i> )-1-(2-Carboxy-6-methylphenyl)diazen-1-ium-2-yl]naphthalen-2-olate

The title compound, C 18 H 14 N 2 O 3 , crystallizes with two zwitterionic molecules ( A and B ) in the asymmetric unit, each featuring an intramolecular N—H...O hydrogen bond. In the extended structure, A + A and B + B carboxylic-acid inversion dimers linked by pairwise O—H...O hydrogen bonds arise, which generate R 2 2 (8) loops in each case. The dimers are linked by weak C—H...π and π–π stacking interactions.

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Journal
IUCrData
Published
2025-12-23
DOI
https://doi.org/10.1107/s2414314625011484
Primary Topic
Synthesis and Properties of Aromatic Compounds
Type
article
Field-Weighted Citation Impact
0.00

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article

1-[( E )-1-(2-Carboxy-6-methylphenyl)diazen-1-ium-2-yl]naphthalen-2-olate

Nabila Benabila, Ouarda Brihi, Souheyla Chetioui, Jean Pierre Djukic
IUCrData
Synthesis and Properties of Aromatic Compounds
article

1-[( E )-1-(2-Carboxy-6-methylphenyl)diazen-1-ium-2-yl]naphthalen-2-olate

Nabila Benabila, Ouarda Brihi, Souheyla Chetioui, Jean Pierre Djukic
article en

Abstract

The title compound, C 18 H 14 N 2 O 3 , crystallizes with two zwitterionic molecules ( A and B ) in the asymmetric unit, each featuring an intramolecular N—H...O hydrogen bond. In the extended structure, A + A and B + B carboxylic-acid inversion dimers linked by pairwise O—H...O hydrogen bonds arise, which generate R 2 2 (8) loops in each case. The dimers are linked by weak C—H...π and π–π stacking interactions.

IUCrDataVol. 10(12)
University Frères Mentouri Constantine 1 (DZ), Institut de Chimie de Strasbourg (FR), Laboratoire de Chimie (FR), University Mohamed Boudiaf of M'sila (DZ), Université Constantine 2 (DZ), Université de Strasbourg (FR)
Université de Strasbourg
Openalex Percentile: Top 33%
Synthesis and Properties of Aromatic Compounds
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