Correction to “Metal‐Free Catalysis Triarylborane‐Catalyzed Alkenylation Reactions of Aryl Esters with Diazo Compounds”

Following a review of spectroscopic data presented in our published work, we confirm a misassignment in the structure of starting material 2j.We sincerely regret this oversight and wish to make the following correction:Error: The structure of 2j, initially assigned based on multinuclear spectroscopic data ( 1 H, 13 C, and 19 F NMR), was incorrectly identified as (E)-1,3-diphenyl-2,2,2-trifluoroacetate. Correction:The correct identity of starting material 2j is oxybis(prop-1-ene-3,1,3-triyl)) tetrabenzene, synthesized as a mixture of cis and trans isomers.Accordingly, the name of 2j in Scheme 1 should be oxybis (prop-1-ene-3,1,3-triyl)) tetrabenzene.The yield of products 3r and 3s have been recalculated as 84% and 91% respectively.The supporting information has been updated accordingly.

Publication Details

Journal
Angewandte Chemie International Edition
Published
2025-12-23
DOI
https://doi.org/10.1002/anie.4747825
Primary Topic
Catalytic Cross-Coupling Reactions
Type
article
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article

Correction to “Metal‐Free Catalysis Triarylborane‐Catalyzed Alkenylation Reactions of Aryl Esters with Diazo Compounds”

Angewandte Chemie International Edition
Catalytic Cross-Coupling Reactions
article

Correction to “Metal‐Free Catalysis Triarylborane‐Catalyzed Alkenylation Reactions of Aryl Esters with Diazo Compounds”

article en

Abstract

Following a review of spectroscopic data presented in our published work, we confirm a misassignment in the structure of starting material 2j.We sincerely regret this oversight and wish to make the following correction:Error: The structure of 2j, initially assigned based on multinuclear spectroscopic data ( 1 H, 13 C, and 19 F NMR), was incorrectly identified as (E)-1,3-diphenyl-2,2,2-trifluoroacetate. Correction:The correct identity of starting material 2j is oxybis(prop-1-ene-3,1,3-triyl)) tetrabenzene, synthesized as a mixture of cis and trans isomers.Accordingly, the name of 2j in Scheme 1 should be oxybis (prop-1-ene-3,1,3-triyl)) tetrabenzene.The yield of products 3r and 3s have been recalculated as 84% and 91% respectively.The supporting information has been updated accordingly.

Angewandte Chemie International EditionVol. 65(5)
Openalex Percentile: Top 33%
Catalytic Cross-Coupling Reactions
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