Disproportionate influence of site disorder on the evolution of magnetic phases in the anti-Heusler alloy <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>Al</mml:mi> <mml:mn>2</mml:mn> </mml:msub> <mml:mi>MnFe<

Anti-Heusler alloys, being a new addition to the Heusler alloys family, exhibit atomic disorders, and almost all of them are reported as a re-entrant spin-glass system. Although such spin-glass feature is generally attributed to the inherent atomic disorder, a comprehensive and extensive investigation on the individual roles of different types of disorders in magnetic interactions remains lacking for any of the reported anti-Heusler systems. As an illustrative case, we have carried out an in-depth experimental as well as theoretical investigation of structural, magnetic, and transport properties of a polycrystalline anti-Heusler alloy, Al$_2$MnFe. While the major atomic disorder is found to be among Fe and Mn atoms, which are randomly distributed among the two octahedral sites, 4$a$ and 4$b$ (B2-type disorder), a relatively small fraction ($\sim$12\%) of Mn atoms also replace Al atoms at the tetrahedral 8$c$ site. Magnetically, the system undergoes two transitions: a paramagnetic to a ferromagnetic transition at $T_{\rm C}\sim$113~K, followed by a spin-glass phase transition below $T_{\rm f}\sim$20~K. Here, the magnetic moment is primarily confined to Mn atoms. Very interestingly, our theoretical analysis reveals that the ferromagnetic spin arrangement remains rather robust in spite of the 50\% disorder of moment-carrying Mn atoms between the two octahedral sites, but a much smaller ($\sim$12\%) cross-distribution of Mn atoms between octahedral and tetrahedral sites are sufficient to impose a reentrant spin-glass state at low temperature. Our analysis brings forth the importance of understanding the role of individual types of swap-disorder on magnetic properties in the anti-Heusler family of materials.

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Journal
Physical review. B./Physical review. B
Published
2025-12-24
DOI
https://doi.org/10.1103/463q-ph2y
Primary Topic
Heusler alloys: electronic and magnetic properties
Type
article
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article

Disproportionate influence of site disorder on the evolution of magnetic phases in the anti-Heusler alloy <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>Al</mml:mi> <mml:mn>2</mml:mn> </mml:msub> <mml:mi>MnFe<

Ashis Kundu, Chandan Mazumdar, Mukul Kabir, Santanu Pakhira et al.
Physical review. B./Physical review. B
Heusler alloys: electronic and magnetic properties
article

Disproportionate influence of site disorder on the evolution of magnetic phases in the anti-Heusler alloy <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>Al</mml:mi> <mml:mn>2</mml:mn> </mml:msub> <mml:mi>MnFe<

Ashis Kundu, Chandan Mazumdar, Mukul Kabir, Santanu Pakhira, Anonymous, V. Raghavendra Reddy
article en

Abstract

Anti-Heusler alloys, being a new addition to the Heusler alloys family, exhibit atomic disorders, and almost all of them are reported as a re-entrant spin-glass system. Although such spin-glass feature is generally attributed to the inherent atomic disorder, a comprehensive and extensive investigation on the individual roles of different types of disorders in magnetic interactions remains lacking for any of the reported anti-Heusler systems. As an illustrative case, we have carried out an in-depth experimental as well as theoretical investigation of structural, magnetic, and transport properties of a polycrystalline anti-Heusler alloy, Al$_2$MnFe. While the major atomic disorder is found to be among Fe and Mn atoms, which are randomly distributed among the two octahedral sites, 4$a$ and 4$b$ (B2-type disorder), a relatively small fraction ($\sim$12\%) of Mn atoms also replace Al atoms at the tetrahedral 8$c$ site. Magnetically, the system undergoes two transitions: a paramagnetic to a ferromagnetic transition at $T_{\rm C}\sim$113~K, followed by a spin-glass phase transition below $T_{\rm f}\sim$20~K. Here, the magnetic moment is primarily confined to Mn atoms. Very interestingly, our theoretical analysis reveals that the ferromagnetic spin arrangement remains rather robust in spite of the 50\% disorder of moment-carrying Mn atoms between the two octahedral sites, but a much smaller ($\sim$12\%) cross-distribution of Mn atoms between octahedral and tetrahedral sites are sufficient to impose a reentrant spin-glass state at low temperature. Our analysis brings forth the importance of understanding the role of individual types of swap-disorder on magnetic properties in the anti-Heusler family of materials.

Physical review. B./Physical review. BVol. 113(1)
Saha Institute of Nuclear Physics (IN), Indian Institute of Science Education and Research Pune (IN), Homi Bhabha National Institute (IN), UGC DAE Consortium for Scientific Research (IN), Maulana Azad National Institute of Technology (IN)
Openalex Percentile: Top 52%
Heusler alloys: electronic and magnetic properties
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