Highly-dispersed ZrO <sub> <i>x</i> </sub> modulates C–O bond activation for boosting CO <sub>2</sub> hydrogenation to higher alcohols
This work reports an efficient strategy for modulating C-O bond activation during CO<sub>2</sub> hydrogenation to C<sub>2+</sub>OH over the Zr-KCuFe catalyst, achieving a space-time yield of 96.7 mg g<sup>-1</sup> h<sup>-1</sup> at 320 °C. A small amount of highly-dispersed ZrO<sub><i>x</i></sub> promotes non-dissociative activation of CO, driving C<sub>2+</sub>OH synthesis with 1.54 times higher activity than unpromoted KCuFe.
Authors
- Guoliang Liu (ORCID: https://orcid.org/0000-0002-6566-7653)
- T. Liu
- Anmin Zheng
- Peng Peng (ORCID: https://orcid.org/0000-0001-6228-8167)
- M. J. Hu
- Lingfeng Wang
Institutions
- Wuhan University of Technology (CN)
- Wuhan University of Science and Technology (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-12-24
- DOI
- https://doi.org/10.1039/d5cc06427a
- Primary Topic
- Catalysts for Methane Reforming
- Type
- article
- Field-Weighted Citation Impact
- 0.00