Temperature-induced phase transformation of cobalt selenide optimizes spin states for enhanced oxygen electrocatalysis

The temperature-induced phase transformation from cobalt diselenide to tricobalt tetraselenide modulates the spin state of cobalt ions, which consequently reduces the reaction energy barrier, ultimately enhancing the catalytic performance for both the oxygen evolution reaction (OER) and oxygen reduction reaction (ORR).

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Publication Details

Journal
Chemical Communications
Published
2025-12-24
DOI
https://doi.org/10.1039/d5cc06408b
Primary Topic
Electrocatalysts for Energy Conversion
Type
article
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article

Temperature-induced phase transformation of cobalt selenide optimizes spin states for enhanced oxygen electrocatalysis

Hongfu Leng, Shucheng Liu, Gangbiao Li, Yi Liu
Chemical Communications
Electrocatalysts for Energy Conversion
article

Temperature-induced phase transformation of cobalt selenide optimizes spin states for enhanced oxygen electrocatalysis

Hongfu Leng, Shucheng Liu, Gangbiao Li, Yi Liu
article en

Abstract

The temperature-induced phase transformation from cobalt diselenide to tricobalt tetraselenide modulates the spin state of cobalt ions, which consequently reduces the reaction energy barrier, ultimately enhancing the catalytic performance for both the oxygen evolution reaction (OER) and oxygen reduction reaction (ORR).

Chemical CommunicationsVol. 62(6)
Guizhou University (CN)
Openalex Percentile: Top 53%
Electrocatalysts for Energy Conversion
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Temperature-induced phase transformation of cobalt selenide optimizes spin states for enhanced oxygen electrocatalysis — Hongfu Leng, Shucheng Liu, et al. · Chemical Communications (2025) | TGRS Research Map | TGRS