Petrography, Geochemistry, and Magmatic Processes of Oligocene-Miocene Tuzla Volcanics, Biga Peninsula, NW Türkiye

The Tuzla area, located in the Ayvacık district of Çanakkale (Biga Peninsula, northwestern Türkiye), hosts a Oligocene-Miocene volcanic system comprising andesitic, dacitic, rhyolitic lavas, trachyandesite, pyroclastics, and ignimbrites, and the Kestanbol Pluton. Petrographic and X-ray diffraction (XRD) analyses indicate that the altered volcanic units are dominated by porphyritic dacitic/rhyodacitic and trachyandesitic rocks, with silicification, iron oxide formation, and opacification. XRD results reveal smectite, smectite–illite/mica, illite–mica, kaolinite, cristobalite–opal, K-feldspar, plagioclase, dolomite, hematite, and quartz as the principal mineral phases. Geochemical data, including rare earth elements (REEs), suggest that fractional crystallization of primary mineral phases played a major role in controlling magmatic evolution. Chondrite-normalized REE patterns display enrichment in light REEs relative to heavy REEs, indicating derivation from a common magma source. K2O–Na2O and (Na2O + K2O)–FeOᵗ–MgO (AFM) diagrams show high-K calc-alkaline, calc-alkaline, and tholeiitic affinities, with most rhyodacite/dacite and all trachyandesite samples plotting in the tholeiitic field. Tectonic discrimination diagrams indicate formation in both volcanic arc and intraplate tectonic settings. Moderate enrichments in Ba and Sr reflect magmatic evolution and source characteristics, whereas the highest concentrations are attributed to post-magmatic fluid–rock interaction. Overall, the Tuzla volcanic rocks originated from a collision-related enriched lithospheric mantle source and subsequently evolved through fractional crystallization and assimilation processes, accompanied by crustal contamination and variable hydrothermal overprint.