Theoretical insight: dual roles of electron-pair donors and acceptors in activating and mediating iodine atom transfer
A DFT study of Lb–BH 2 + -mediated C–I activation, Lb–BH 2 ˙-facilitated XAT and alkyl radical generation, and [Cu( ii )]-mediated C–N bond formation through combined one-electron oxidation and two-electron reduction.
Authors
- Taiming Bai
- Ming Lei (ORCID: https://orcid.org/0000-0002-7340-2970)
- Hui Li
Institutions
- State Ethnic Affairs Commission (CN)
- Beijing University of Chemical Technology (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2025-12-23
- DOI
- https://doi.org/10.1039/d5qo01593f
- Primary Topic
- Radical Photochemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00