Thermodynamic stability and reactivity of amorphised tricalcium silicate

Using a model for C-S-H growth kinetics in combination with calorimetry measurements, we show that amorphised tricalcium silicate is more thermodynamically stable than its crystalline form. However, the onset of the hydration reaction occurs more quickly in amorphised tricalcium silicate compared to its crystalline form.

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Publication Details

Journal
Chemical Communications
Published
2025-12-23
DOI
https://doi.org/10.1039/d5cc05691h
Primary Topic
Mesoporous Materials and Catalysis
Type
article
Field-Weighted Citation Impact
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article

Thermodynamic stability and reactivity of amorphised tricalcium silicate

Karen Scrivener, Alastair T. M. Marsh, Alexander Pisch, Thiago R. S. Nobre et al.
Chemical Communications
Mesoporous Materials and Catalysis
article

Thermodynamic stability and reactivity of amorphised tricalcium silicate

Karen Scrivener, Alastair T. M. Marsh, Alexander Pisch, Thiago R. S. Nobre, Marjorie Etchevers
article en

Abstract

Using a model for C-S-H growth kinetics in combination with calorimetry measurements, we show that amorphised tricalcium silicate is more thermodynamically stable than its crystalline form. However, the onset of the hydration reaction occurs more quickly in amorphised tricalcium silicate compared to its crystalline form.

Chemical CommunicationsVol. 62(6)
Institut polytechnique de Grenoble (FR), Centre National de la Recherche Scientifique (FR), Universidade de São Paulo (BR), École Polytechnique Fédérale de Lausanne (CH), Université Grenoble Alpes (FR)
Openalex Percentile: Top 48%
Mesoporous Materials and Catalysis
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