Effects of Thermal Cycling and Environmental Exposure on Mechanical Properties of 6061 and 7075 Aluminum Alloys

This work quantifies the environmental sensitivity of tartaric–sulfuric acid (TSA) anodized and sealed 6061 and 7075 aluminum. Five alloy–temper states (6061-T4, 6061-T62, 7075-T0, 7075-T62, and 7075-T73) were TSA-treated, pore sealed and then exposed for eight weeks (56 days) to ambient air, 11 wt.% NaCl brine, or a microbiological medium, with weekly +20 °C/−20 °C freeze–thaw cycles. Tensile tests assessing yield strength, ultimate strength, and elongation were conducted. Strength losses were modest in ambient conditions (<5%) but increased to ≈5–10% for yield and ≈2–9% for ultimate under saline and microbial conditions, particularly in the annealed 7075-T0 and peak-aged 7075-T62 states. Ductility was more sensitive, declining up to ≈30% for 6061-T4 and 6061-T62 in harsh media. Permutation-based inference within an additive screening model indicated that environmental exposure is strongly associated with the dominant share of the observed variability (R2env ≈ 0.91–0.93 for yield, ultimate strength, and elongation), within the limits of the present dataset. These results suggest that freeze–thaw cycling, chloride exposure, and microbiological activity are consistent with the observed degradation trends. Over-aged 7075-T73 retained properties better than T62, highlighting the roles of temper and pore sealing quality in cold, saline, and microbiologically active service.