Gamma and Neutron Irradiation Effects on Wavelength Shifting Materials for Nuclear and High Energy Physics Applications

Wavelength-shifting (WLS) materials are used in radiation detectors to convert ultraviolet photons into visible light, enabling improved photon detection in systems such as scintillators and optical diagnostics for nuclear fusion devices. However, the long-term performance of these materials under radiation is still a critical issue in high-dose environments. In this work, we investigated the radiation tolerance of three WLS compounds (TPB, NOL1, and SB2001), each deposited on reflective substrates (ESR and E-PTFE), resulting in six distinct WLS/substrate systems. The samples underwent gamma irradiation at absorbed doses of 100 kGy, 500 kGy, and 1000 kGy, as well as fast neutron (14.1 MeV) irradiation up to a fluence of 1.9 × 1013 n/cm2. Qualitative photoluminescence and reflectance measurements were performed before and after irradiation to assess changes in optical performance. Gamma exposure caused spectral broadening in several samples, particularly those with TPB and SB2001, with variations of the two metrics used to compare the performance of the materials exceeding 10% at the highest doses. Neutron-induced effects were generally weaker and did not exhibit a clear fluence dependence. Reflectance degradation was also observed, with variations depending on both the WLS material and the deposition method. These findings contribute to the understanding of WLS material stability under radiation and support their qualification for use in optical components exposed to harsh nuclear environments.