Flame Retardancy and Smoke Suppression of Warm-Mix Asphalt Binder Containing Various Flame Retardants

This study investigated the synergistic mechanisms of flame retardancy and smoke suppression exhibited by a novel ternary additive in warm-mix asphalt (WMA). The ternary additive consisted of aluminum hydroxide (ATH), organic montmorillonite (OMMT), and expandable graphite (EG). A comprehensive experimental program was conducted, encompassing limiting oxygen index (LOI) testing, cone calorimeter testing, thermogravimetric analysis (TGA), and scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM–EDS). The results showed that incorporation of 6 wt% of the ternary additive (by mass of the asphalt binder) markedly improved the fire resistance of the WMA. The LOI increased from 19.8% (neat asphalt) to 25.2%. Cone calorimeter tests revealed a 23.9% increase in time to ignition, a 24.2% reduction in peak heat release rate, and a 47.5% decrease in total smoke production. These improvements are attributed to a synergistic mechanism involving the endothermic decomposition of ATH, the char-promoting effect of OMMT, and the intumescent expansion of expandable graphite (EG) forming a compact insulating barrier, which collectively inhibit combustion and smoke release. The ternary additive exhibits considerable promise as an effective flame-retardant modifier for enhancing the fire safety of warm-mix asphalt pavements, especially in high-risk scenarios such as tunnels.