Thermal Insulation and Compressive Strength of Lightweight Geopolymer Foam Concrete Exposed to Accelerated Weathering by Carbonation, Salt Fog and UV Light

This study investigates the deterioration of the thermal and mechanical properties of geopolymer foam concrete (GFC) subjected to accelerated weathering through carbonation, salt fog, and UV radiation. GFC blocks were synthesized using metakaolin as the aluminosilicate precursor, activated with an alkaline solution consisting of 8 M NaOH and sodium silicate (Na<sub>2</sub>SiO<sub>3</sub>) at a NaOH/Na<sub>2</sub>SiO<sub>3</sub> ratio of 0.51 wt.%. A 30% (<i>v</i>/<i>v</i>) H<sub>2</sub>O<sub>2</sub> solution served as the foaming agent, and olive oil was used as the surfactant. Accelerated carbonation tests were conducted at 25 ± 3 °C and 40 ± 3 °C, under 60 ± 5% relative humidity and 5% CO<sub>2</sub>, with carbonation depth, carbonation percentage, density, porosity, and thermal conductivity evaluated over a 7-day period. In parallel, specimens were exposed to salt fog and UV radiation for 12 weeks in accordance with ASTM B117-19 and ASTM G154-23, respectively. Compressive strength was monitored every week throughout the exposure period. Results show that carbonation temperature governs the type and kinetics of carbonate formation. The carbonation process, at 40 °C for 7 days, increased the density and reduced the porosity of GFC, resulting in a ~48% increase in thermal conductivity. Salt fog exposure led to severe mechanical degradation, with NaCl penetration reducing compressive strength by 69%. In contrast, UV radiation caused only minor deterioration, decreasing compressive strength by up to 7%, likely due to surface-level carbonation.

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Journal
Materials
Published
2025-12-19
DOI
https://doi.org/10.3390/ma19010012
Primary Topic
Concrete and Cement Materials Research
Type
article
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article

Thermal Insulation and Compressive Strength of Lightweight Geopolymer Foam Concrete Exposed to Accelerated Weathering by Carbonation, Salt Fog and UV Light

Víctor M. Orozco-Carmona, S.P. Arredondo-Rea, Andrés Castro-Beltrán, Ramón Corral Higuera et al.
Materials
Concrete and Cement Materials Research
article

Thermal Insulation and Compressive Strength of Lightweight Geopolymer Foam Concrete Exposed to Accelerated Weathering by Carbonation, Salt Fog and UV Light

Víctor M. Orozco-Carmona, S.P. Arredondo-Rea, Andrés Castro-Beltrán, Ramón Corral Higuera, Anabel De la Cruz-Delgado, Gabriela A. de la Rosa-Corral, Alfredo Martinez-Garcia
article en

Abstract

This study investigates the deterioration of the thermal and mechanical properties of geopolymer foam concrete (GFC) subjected to accelerated weathering through carbonation, salt fog, and UV radiation. GFC blocks were synthesized using metakaolin as the aluminosilicate precursor, activated with an alkaline solution consisting of 8 M NaOH and sodium silicate (Na<sub>2</sub>SiO<sub>3</sub>) at a NaOH/Na<sub>2</sub>SiO<sub>3</sub> ratio of 0.51 wt.%. A 30% (<i>v</i>/<i>v</i>) H<sub>2</sub>O<sub>2</sub> solution served as the foaming agent, and olive oil was used as the surfactant. Accelerated carbonation tests were conducted at 25 ± 3 °C and 40 ± 3 °C, under 60 ± 5% relative humidity and 5% CO<sub>2</sub>, with carbonation depth, carbonation percentage, density, porosity, and thermal conductivity evaluated over a 7-day period. In parallel, specimens were exposed to salt fog and UV radiation for 12 weeks in accordance with ASTM B117-19 and ASTM G154-23, respectively. Compressive strength was monitored every week throughout the exposure period. Results show that carbonation temperature governs the type and kinetics of carbonate formation. The carbonation process, at 40 °C for 7 days, increased the density and reduced the porosity of GFC, resulting in a ~48% increase in thermal conductivity. Salt fog exposure led to severe mechanical degradation, with NaCl penetration reducing compressive strength by 69%. In contrast, UV radiation caused only minor deterioration, decreasing compressive strength by up to 7%, likely due to surface-level carbonation.

MaterialsVol. 19(1)
Universidad Autónoma de Sinaloa (MX), Centro de Investigación en Materiales Avanzados (MX)
Openalex Percentile: Top 38%
Concrete and Cement Materials Research
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