The shape of ribbons: from polymers to surfaces

Ribbons are a subset of polymerized networks that occupy an intermediate space between polymers and surfaces. We perform extensive numerical simulations to understand how to interpolate the statistical properties of ribbons across the two limits by studying their behavior as a function of their widths and bending rigidities, taking into consideration both ideal and self-avoiding ribbons. We map out a two-dimensional phase diagram of the morphology of ideal ribbons, and uncover the onset of a crumpling transition for ribbons of sufficiently large width. We also discuss the onset width above which a ribbon behaves effectively as a surface. Finally, we suggest scaling laws and functional forms that properly link and interpolate the shape of self-avoiding polymers to that of self-avoiding surfaces.

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Publication Details

Journal
Soft Matter
Published
2025-12-22
DOI
https://doi.org/10.1039/d5sm01001b
Primary Topic
Polymer Surface Interaction Studies
Type
article
Field-Weighted Citation Impact
0.00

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article

The shape of ribbons: from polymers to surfaces

Albert D Chen, Angelo Cacciuto, Mahesh Gandikota
Soft Matter
Polymer Surface Interaction Studies
article

The shape of ribbons: from polymers to surfaces

Albert D Chen, Angelo Cacciuto, Mahesh Gandikota
article en

Abstract

Ribbons are a subset of polymerized networks that occupy an intermediate space between polymers and surfaces. We perform extensive numerical simulations to understand how to interpolate the statistical properties of ribbons across the two limits by studying their behavior as a function of their widths and bending rigidities, taking into consideration both ideal and self-avoiding ribbons. We map out a two-dimensional phase diagram of the morphology of ideal ribbons, and uncover the onset of a crumpling transition for ribbons of sufficiently large width. We also discuss the onset width above which a ribbon behaves effectively as a surface. Finally, we suggest scaling laws and functional forms that properly link and interpolate the shape of self-avoiding polymers to that of self-avoiding surfaces.

Soft MatterVol. 22(8)
Tata Institute of Fundamental Research (IN), International Centre for Theoretical Sciences (IN), Columbia University (US)
National Science Foundation, Division of Materials Research
Openalex Percentile: Top 41%
Polymer Surface Interaction Studies
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