Cycloaddition of Nitrile Imine to (R)-(–)-Carvone

Cycloaddition of (R)-(–)-carvone and nitrile imine generated in situ from N-phenylbenzenecarbo­hydrazonoyl chloride in the presence of triethylamine afforded (3aS,5R,7aS)-7a-methyl-1,3-diphenyl-5-(prop-1-en-2-yl)-1,3a,4,5,6,7a-hexahydro-7H-indazol-7-one as the major product. Its structure was determined by spectral methods.

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Publication Details

Journal
Russian Journal of Organic Chemistry
Published
2025-10-01
DOI
https://doi.org/10.1134/s1070428025603097
Primary Topic
Synthesis and Characterization of Pyrroles
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article
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article

Cycloaddition of Nitrile Imine to (R)-(–)-Carvone

N. R. Yamaletdinova, R. R. Safargalin, R. R. Gataullin
Russian Journal of Organic Chemistry
Synthesis and Characterization of Pyrroles
article

Cycloaddition of Nitrile Imine to (R)-(–)-Carvone

N. R. Yamaletdinova, R. R. Safargalin, R. R. Gataullin
article en

Abstract

Cycloaddition of (R)-(–)-carvone and nitrile imine generated in situ from N-phenylbenzenecarbo­hydrazonoyl chloride in the presence of triethylamine afforded (3aS,5R,7aS)-7a-methyl-1,3-diphenyl-5-(prop-1-en-2-yl)-1,3a,4,5,6,7a-hexahydro-7H-indazol-7-one as the major product. Its structure was determined by spectral methods.

Russian Journal of Organic ChemistryVol. 61(10)
Ufa Institute of Chemistry (RU)
Clean water and sanitation
Openalex Percentile: Top 34%
Synthesis and Characterization of Pyrroles
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Cycloaddition of Nitrile Imine to (R)-(–)-Carvone — N. R. Yamaletdinova, R. R. Safargalin, et al. · Russian Journal of Organic Chemistry (2025) | TGRS Research Map | TGRS