Chemodivergent Photocatalytic Reaction of Sodium Benzenesulfinate and 2-Iodopyridine

Chemodivergent synthesis of 2-(benzenesulfonyl)pyridine and pyridin-2-yl benzenesulfinate from 2-iodopyridine and sodium benzenesulfinate has been achieved using visible light nickel/photoredox catalysis (λ 450 nm, 30 W). The selectivity for C–S or C–O coupling has been found to depend on the photocatalyst nature.

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Publication Details

Journal
Russian Journal of Organic Chemistry
Published
2025-10-01
DOI
https://doi.org/10.1134/s1070428025604686
Primary Topic
Sulfur-Based Synthesis Techniques
Type
article
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article

Chemodivergent Photocatalytic Reaction of Sodium Benzenesulfinate and 2-Iodopyridine

I. P. Beletskaya, V. A. Ionova, A. S. Abel
Russian Journal of Organic Chemistry
Sulfur-Based Synthesis Techniques
article

Chemodivergent Photocatalytic Reaction of Sodium Benzenesulfinate and 2-Iodopyridine

I. P. Beletskaya, V. A. Ionova, A. S. Abel
article en

Abstract

Chemodivergent synthesis of 2-(benzenesulfonyl)pyridine and pyridin-2-yl benzenesulfinate from 2-iodopyridine and sodium benzenesulfinate has been achieved using visible light nickel/photoredox catalysis (λ 450 nm, 30 W). The selectivity for C–S or C–O coupling has been found to depend on the photocatalyst nature.

Russian Journal of Organic ChemistryVol. 61(10)
Russian Academy of Sciences (RU), Lomonosov Moscow State University (RU), Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences (RU), A.V. Topchiev Institute of Petrochemical Synthesis (RU)
Clean water and sanitation
Openalex Percentile: Top 34%
Sulfur-Based Synthesis Techniques
DOISourceOpenAlex
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