Modeling Carbonation Depth in Hardened Alkali-Activated Slag Under Accelerated Curing: A Multi-Physics Finite Element Approach

This study develops a numerical model based on a multi-physics coupled finite element method to predict the carbonation depth of hardened alkali-activated slag under accelerated carbonation curing conditions. Drawing on existing literature data, the chemical composition and porosity of alkali-activated slag at different ages were determined under non-carbonation conditions, supported by thermodynamic and kinetic analyses of alkali activation reactions. A differential equation governing CO2 diffusion—incorporating diffusion rate, diffusion coefficient, carbonation reaction rate, and related parameters—was established using Fick’s second law. The influence of humidity and carbonation degree on the reaction rate was quantified, and a correlation between carbonation degree and porosity was derived through thermodynamic analysis. These equations were solved numerically in a two-dimensional domain to predict carbonation depth over time. The results demonstrate that the proposed model, using only raw material composition and curing conditions, achieves reasonable accuracy in predicting carbonation depth.