Modulating the coordinated microenvironments of single Co( <scp>ii</scp> ) sites in metal–organic frameworks for harnessing acyl radicals
The microenvironments of single Co( ii ) sites in UiO-67-Ir-CoX 2 (X = NO 3 , Cl, OAc, CF 3 SO 3 ) can be modulated by modifying the coordinating anions, which show excellent activity in the synthesis of 4 H -benzo[ b ]pyrans via acyl radical utilization.
Institutions
- Zhaoqing University (CN)
- Jiaxing University (CN)
- Wuyi University (CN)
- Wuyi University (CN)
Publication Details
- Journal
- Inorganic Chemistry Frontiers
- Published
- 2025-12-18
- DOI
- https://doi.org/10.1039/d5qi01688f
- Primary Topic
- Metal-Organic Frameworks: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00