Enhancing iodine capture through a zirconium-based metal–organic cage featuring functionalized indole units

This study develops an indole-functionalized zirconium-based metal-organic cage (Zr-MOC-Indole) for efficient iodine capture. The material exhibits high iodine vapor uptake and effective iodine removal from solution. Experimental and theoretical analyses reveal a synergistic adsorption mechanism involving charge transfer and hydrogen bonding, stabilizing polyiodides within the structure.

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Publication Details

Journal
Chemical Communications
Published
2025-12-17
DOI
https://doi.org/10.1039/d5cc05987a
Primary Topic
Covalent Organic Framework Applications
Type
article
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article

Enhancing iodine capture through a zirconium-based metal–organic cage featuring functionalized indole units

Chemical Communications
Covalent Organic Framework Applications
article

Enhancing iodine capture through a zirconium-based metal–organic cage featuring functionalized indole units

article en

Abstract

This study develops an indole-functionalized zirconium-based metal-organic cage (Zr-MOC-Indole) for efficient iodine capture. The material exhibits high iodine vapor uptake and effective iodine removal from solution. Experimental and theoretical analyses reveal a synergistic adsorption mechanism involving charge transfer and hydrogen bonding, stabilizing polyiodides within the structure.

Chemical CommunicationsVol. 62(6)
Hefei University of Technology (CN)
Openalex Percentile: Top 49%
Covalent Organic Framework Applications
DOISourceOpenAlex
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Enhancing iodine capture through a zirconium-based metal–organic cage featuring functionalized indole units · Chemical Communications (2025) | TGRS Research Map | TGRS