Recent progress of scanning tunneling microscopy/spectroscopy study of pair density wave in superconductors

A pair density wave (PDW) is a superconducting state characterized by an order parameter with finite center-of-mass momentum in the absence of an external magnetic field, thereby breaking the conventional translational symmetry in homogeneous superconductors. It is proposed that PDWs emerge from magnetic interactions, strong electron−electron correlations, and their interplay with competing orders. In this review, we highlight recent advances in the detection and study of PDWs using scanning tunneling microscopy and spectroscopy (STM/STS). We focus on how the signatures of PDWs have been experimentally visualized across a variety of extraordinary superconductors, including iron-based superconductors, cuprate superconductors, spin-triplet superconductors, kagome-lattice superconductors, and transition metal dichalcogenides. Beginning with an introduction to the fundamental concept of PDWs and the unique capabilities of STM/STS — particularly its atomic-scale spatial resolution and advanced data analysis techniques — we discuss key experimental findings, including the direct visualization of charge density modulations associated with PDWs. Finally, we address emerging challenges and future directions, aiming to inspire future research into the nature of PDWs in superconductors.