The motion of a surfactant-laden bubble in a channel or a Hele-Shaw cell

We investigate how the addition of surfactant affects the governing equations for a bubble in a two-dimensional channel in the small-capillary-number limit. In the limit where the time scale for absorption of surfactant is much shorter than the time scales for transport of surfactant along the surface of the bubble, we derive a set of idealised free-surface boundary conditions that capture the effects of surfactant in a single dimensionless ‘elasticity parameter’, and apply them to the front and rear of the bubble separately. At the front of the bubble, there are three regions of interest: the front cap, the thin film region and a transition region that smoothly connects the other two regions. Through matched asymptotic expansions, we derive predictions for the thin film height and the pressure drop across the front meniscus. We find that the viscous pressure drop across the front meniscus is always larger for a surfactant-laden bubble than for a surfactant-free bubble, by an order-one factor of up to $4^{2/3}$ . Using a similar analysis at the rear of the bubble, we find that the viscous pressure drop across the rear meniscus is also always larger in magnitude for a surfactant-laden bubble than for a surfactant-free bubble, again up to a maximum factor of $4^{2/3}$ . Finally, we use these results to show that, for the same flow conditions, an isolated surfactant-laden bubble in a Hele-Shaw cell will travel more slowly than an isolated surfactant-free bubble.