The Complete Solution to the Glass Transition: A Unified Energy–Topology Landscape (ETL) Framework

The glass transition — the dramatic dynamical arrest of supercooled liquids into amorphous solids — remains one of the deepest unsolved problems in condensed-matter physics. Competing paradigms (thermodynamic Random First-Order Transition [RFOT], kinetically constrained/facilitation models, frustration-based approaches, and energy landscape viewpoints) each capture facets of the phenomenon but fail to produce a single, predictive, experimentally falsifiable theory. Here I propose the Energy–Topology Landscape (ETL) Unification, a theoretical and computational framework that synthesizes thermodynamics, topology of configuration space, and dynamical facilitation into a single continuum theory. In ETL the glass transition is not a single mechanism but an emergent consequence of (1) a proliferation of high-dimensional topological bottlenecks in the potential-energy landscape as cooling proceeds, (2) a finite but vanishingly small measure of accessible configuration-space pathways that enforce hierarchical facilitation, and (3) a thermodynamic drift toward deep meta-basins whose internal ruggedness controls low-temperature vibrational anomalies. ETL yields closed-form scaling relations for relaxation times, a microscopic origin for the boson peak and non-linear elastic response, and precise experimental signatures (specific heat, non-linear susceptibility, ultrastable glass fingerprints). I provide a mathematical formalism, numerical algorithmic recipes, and a program of decisive experiments. I argue that, once the proposed predictions are verified (or falsified) by the community, the ETL framework will constitute a comprehensive resolution to the glass problem.

Publication Details

Journal
AfricArXiv (OSF Preprints)
Published
2025-11-27
DOI
https://doi.org/10.60763/africarxiv/10332
Primary Topic
Material Dynamics and Properties
Type
article
Field-Weighted Citation Impact
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article

The Complete Solution to the Glass Transition: A Unified Energy–Topology Landscape (ETL) Framework

AfricArXiv (OSF Preprints)
Material Dynamics and Properties
article

The Complete Solution to the Glass Transition: A Unified Energy–Topology Landscape (ETL) Framework

article en

Abstract

The glass transition — the dramatic dynamical arrest of supercooled liquids into amorphous solids — remains one of the deepest unsolved problems in condensed-matter physics. Competing paradigms (thermodynamic Random First-Order Transition [RFOT], kinetically constrained/facilitation models, frustration-based approaches, and energy landscape viewpoints) each capture facets of the phenomenon but fail to produce a single, predictive, experimentally falsifiable theory. Here I propose the Energy–Topology Landscape (ETL) Unification, a theoretical and computational framework that synthesizes thermodynamics, topology of configuration space, and dynamical facilitation into a single continuum theory. In ETL the glass transition is not a single mechanism but an emergent consequence of (1) a proliferation of high-dimensional topological bottlenecks in the potential-energy landscape as cooling proceeds, (2) a finite but vanishingly small measure of accessible configuration-space pathways that enforce hierarchical facilitation, and (3) a thermodynamic drift toward deep meta-basins whose internal ruggedness controls low-temperature vibrational anomalies. ETL yields closed-form scaling relations for relaxation times, a microscopic origin for the boson peak and non-linear elastic response, and precise experimental signatures (specific heat, non-linear susceptibility, ultrastable glass fingerprints). I provide a mathematical formalism, numerical algorithmic recipes, and a program of decisive experiments. I argue that, once the proposed predictions are verified (or falsified) by the community, the ETL framework will constitute a comprehensive resolution to the glass problem.

AfricArXiv (OSF Preprints)
Openalex Percentile: Top 50%
Material Dynamics and Properties
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