ВИДАЛЕННЯ ІОНІВ МАГНІЮ З ВОДИ В ЕЛЕКТРОЛІЗЕРАХ З ДІАФРАГМОЮ

This work presents the results of a study on the applicability of electrolysis in two-chamber electrolyzers with a diaphragm for reducing magnesium hardness in aqueous solutions. It was established that conducting electrolysis for 10–60 minutes allows for a reduction in the initial water hardness from 10–30 mg-eq/dm³ to 7 mg-eq/dm³, which meets the current regulatory standards for potable water. The primary factor contributing to hardness reduction is the increase in pH in the cathodic compartment. A slight decrease in hardness was also observed in the anodic compartment, likely due to the diffusion of magnesium ions through the diaphragm into the cathodic chamber. When the electrolyzer is powered by a stabilized DC voltage source, a significant change in current density on the electrodes is observed during electrolysis, caused by the changing conductivity of the solution in the cathodic compartment. Under a constant chemical composition of water, this relationship may be used to monitor the progress of the electrolysis process. The promising results encourage further research in this direction.

Publication Details

Journal
Scientific periodicals of Ukraine
Published
2025-11-10
Primary Topic
Magnesium Alloys: Properties and Applications
Type
article
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article

ВИДАЛЕННЯ ІОНІВ МАГНІЮ З ВОДИ В ЕЛЕКТРОЛІЗЕРАХ З ДІАФРАГМОЮ

Scientific periodicals of Ukraine
Magnesium Alloys: Properties and Applications
article

ВИДАЛЕННЯ ІОНІВ МАГНІЮ З ВОДИ В ЕЛЕКТРОЛІЗЕРАХ З ДІАФРАГМОЮ

article en

Abstract

This work presents the results of a study on the applicability of electrolysis in two-chamber electrolyzers with a diaphragm for reducing magnesium hardness in aqueous solutions. It was established that conducting electrolysis for 10–60 minutes allows for a reduction in the initial water hardness from 10–30 mg-eq/dm³ to 7 mg-eq/dm³, which meets the current regulatory standards for potable water. The primary factor contributing to hardness reduction is the increase in pH in the cathodic compartment. A slight decrease in hardness was also observed in the anodic compartment, likely due to the diffusion of magnesium ions through the diaphragm into the cathodic chamber. When the electrolyzer is powered by a stabilized DC voltage source, a significant change in current density on the electrodes is observed during electrolysis, caused by the changing conductivity of the solution in the cathodic compartment. Under a constant chemical composition of water, this relationship may be used to monitor the progress of the electrolysis process. The promising results encourage further research in this direction.

Scientific periodicals of Ukraine
Clean water and sanitation
Openalex Percentile: Top 47%
Magnesium Alloys: Properties and Applications
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