Discovery of a New Chemical Reaction: the Formation of Oxygen and Silicon Containing Rings from a Non-metal Catalyst

Alkene hydrosilylation reactions have been performed for over 75 years. However, since 1957 all reported alkene hydrosilylation reactions have utilized metal catalysts. In this essay, I detail how I made the discovery of doing this type of reaction using the non-metal catalyst called TBAT (tetrabutylammonium difluorotriphenylsilicate). While I unfold the discovery I also go into detail on some of the laboratory techniques I use as an organic chemist such as column chromatography and proton NMR (nuclear magnetic resonance). The second half of the piece is dedicated to detailing how I was able to trouble shoot the chemistry when the TBAT started to get exposed to water and the alkenes were reduced.

Publication Details

Journal
Western CEDAR (Western Washington University)
Published
2025-04-01
Primary Topic
Organoboron and organosilicon chemistry
Type
article
Field-Weighted Citation Impact
0.00
Controls
|||
ALL TIME
JAN
FEB
MAR
APR
MAY
JUN
JUL
AUG
SEP
OCT
article

Discovery of a New Chemical Reaction: the Formation of Oxygen and Silicon Containing Rings from a Non-metal Catalyst

Western CEDAR (Western Washington University)
Organoboron and organosilicon chemistry
article

Discovery of a New Chemical Reaction: the Formation of Oxygen and Silicon Containing Rings from a Non-metal Catalyst

article en

Abstract

Alkene hydrosilylation reactions have been performed for over 75 years. However, since 1957 all reported alkene hydrosilylation reactions have utilized metal catalysts. In this essay, I detail how I made the discovery of doing this type of reaction using the non-metal catalyst called TBAT (tetrabutylammonium difluorotriphenylsilicate). While I unfold the discovery I also go into detail on some of the laboratory techniques I use as an organic chemist such as column chromatography and proton NMR (nuclear magnetic resonance). The second half of the piece is dedicated to detailing how I was able to trouble shoot the chemistry when the TBAT started to get exposed to water and the alkenes were reduced.

Western CEDAR (Western Washington University)
Clean water and sanitation
Openalex Percentile: Top 35%
Organoboron and organosilicon chemistry
AI Navigator

Ask Laika to Summarize, Analyze, and Connect papers live on the map.

Summarize Papers & Methodologies

Extract key findings, datasets, and comparative methods across publications.

Benchmark Rankings & Visual Analytics

Rank top research institutions, authors, funders, topics, and journals by Field-Weighted Citation Impact (FWCI) and paper volume with instant charts.

Connect Distant Disciplines

Bridge topological clusters on the map to find hidden collaborative intersections.

Discovery of a New Chemical Reaction: the Formation of Oxygen and Silicon Containing Rings from a Non-metal Catalyst · Western CEDAR (Western Washington University) (2025) | TGRS Research Map | TGRS