Investigating aerosols as a way to reconcile K2-18 b JWST MIRI and NIRISS/NIRSpec observations

Recent JWST observations of the temperate sub-Neptune K2-18 b with NIRISS SOSS/NIRSpec G395H and MIRI LRS have yielded apparently inconsistent results: the MIRI spectra exhibit spectral features nearly twice as large as those seen at shorter wavelengths, challenging the high-metallicity, CH4-rich nonequilibrium model that fits the NIRISS/NIRSpec data. We performed a suite of atmospheric retrievals on both datasets, including free-chemistry, nonequilibrium, and aerosol models, using laboratory-derived complex refractive indices for a variety of photochemical haze analogs. Free retrievals systematically output lower metallicities than inferred by self-consistent chemical disequilibrium models, and the inclusion of absorbing aerosols, especially CH4-dominated, nitrogen-poor tholins, can further reduce the inferred metallicity by over an order of magnitude. These hazes reproduce the observed NIRISS slope through scattering and match MIRI features via C–H bending absorption near 7 μm, while yielding particle properties consistent with photochemical production in H2-rich atmospheres. Although their inclusion improves the joint fit and reduces tension between datasets, it also significantly lowers the retrieved CH4 abundance, highlighting degeneracies between metallicity, composition, and aerosol properties. Our results underscore the importance of aerosol absorption in interpreting temperate sub-Neptune spectra and motivate future JWST observations and laboratory work to break these degeneracies.