Synthesis, crystal structure and Hirshfeld surface of bis(acetato-κ <sup>2</sup> <i>O</i> , <i>O</i> ′)(2-benzyl-1 <i>H</i> -benzimidazole-κ <i>N</i> <sup>3</sup> )copper(II)
The title copper(II) complex, [Cu(C<sub>2</sub>H<sub>3</sub>O<sub>2</sub>)<sub>2</sub>(C<sub>14</sub>H<sub>12</sub>N<sub>2</sub>)<sub>2</sub>], was synthesized and structurally characterized. It crystallizes in the monoclinic space group <i>P2</i> <sub>1</sub> <i>/n</i> with one mol-ecule per asymmetric unit. The Cu<sup>2+</sup> ion exhibits a distorted octa-hedral (4 + 2) coordination geometry. The crystal packing is consolidated by N-H⋯O hydrogen bonds and C-H⋯π inter-actions. Hirshfeld surface analysis indicates that H⋯H, H⋯C/C⋯H and O⋯H/H⋯O contacts are the major contributors to the crystal packing.
Institutions
- Yunusov Institute of the Chemistry of Plant Substances (UZ)
- Tashkent Pediatric Medical Institute (UZ)
- National University of Uzbekistan (UZ)
- Tashkent State University of Economics (UZ)
Publication Details
- Journal
- Acta Crystallographica Section E Crystallographic Communications
- Published
- 2025-12-04
- DOI
- https://doi.org/10.1107/s2056989025010813
- Primary Topic
- Crystal structures of chemical compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.00