A proposed route to metastable room-temperature superconductivity in Li₂MgB₂H₁₈

The realization of room-temperature superconductivity at ambient pressure remains the ultimate goal of condensed matter physics. While high-pressure superhydrides (e.g., 𝐿𝑎𝐻10) have achieved high critical temperatures (Tc), they lose stability upon decompression. Here, I predict a novel ternary clathrate structure, 𝐿𝑖2 𝑀𝑔 𝐵2𝐻18, designed to maintain high-Tc superconductivity at 0GPa via a "kinetic locking" mechanism. First-principles calculations reveal that a rigid Boron-Magnesium host lattice can chemically confine dense hydrogen clusters, mimicking the effects of external pressure. I estimate a Tc of ~298 K driven by strong electron-phonon coupling (𝜆≈2.6). Furthermore, I propose a cryogenic decompression protocol ("Cryo-Lock") to synthesize and stabilize this metastable phase for ambient-pressure operation

Publication Details

Journal
Zenodo (CERN European Organization for Nuclear Research)
Published
2026-09-05
DOI
https://doi.org/10.5281/zenodo.17776324
Primary Topic
High-pressure geophysics and materials
Type
article
Field-Weighted Citation Impact
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article

A proposed route to metastable room-temperature superconductivity in Li₂MgB₂H₁₈

Zenodo (CERN European Organization for Nuclear Research)
High-pressure geophysics and materials
article

A proposed route to metastable room-temperature superconductivity in Li₂MgB₂H₁₈

article en

Abstract

The realization of room-temperature superconductivity at ambient pressure remains the ultimate goal of condensed matter physics. While high-pressure superhydrides (e.g., 𝐿𝑎𝐻10) have achieved high critical temperatures (Tc), they lose stability upon decompression. Here, I predict a novel ternary clathrate structure, 𝐿𝑖2 𝑀𝑔 𝐵2𝐻18, designed to maintain high-Tc superconductivity at 0GPa via a "kinetic locking" mechanism. First-principles calculations reveal that a rigid Boron-Magnesium host lattice can chemically confine dense hydrogen clusters, mimicking the effects of external pressure. I estimate a Tc of ~298 K driven by strong electron-phonon coupling (𝜆≈2.6). Furthermore, I propose a cryogenic decompression protocol ("Cryo-Lock") to synthesize and stabilize this metastable phase for ambient-pressure operation

Zenodo (CERN European Organization for Nuclear Research)
Openalex Percentile: Top 99%
High-pressure geophysics and materials
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