Direct allylic C(sp <sup>3</sup> )–H acylation of alkenes <i>via</i> metallaphotoredox catalysis using carboxylic acids

A nickel/photoredox dual catalytic system that enables direct allylic C(sp 3 )–H acylation of unactivated alkenes with free carboxylic acids has been developed, providing a more straightforward and versatile approach to β,γ-unsaturated ketones.

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Publication Details

Journal
Green Chemistry
Published
2025-11-24
DOI
https://doi.org/10.1039/d5gc04541j
Primary Topic
Catalytic C–H Functionalization Methods
Type
article
Field-Weighted Citation Impact
0.00
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article

Direct allylic C(sp 3 )–H acylation of alkenes via metallaphotoredox catalysis using carboxylic acids

Green Chemistry
Catalytic C–H Functionalization Methods
article

Direct allylic C(sp 3 )–H acylation of alkenes via metallaphotoredox catalysis using carboxylic acids

article en

Abstract

A nickel/photoredox dual catalytic system that enables direct allylic C(sp 3 )–H acylation of unactivated alkenes with free carboxylic acids has been developed, providing a more straightforward and versatile approach to β,γ-unsaturated ketones.

Green ChemistryVol. 28(1)
South China Agricultural University (CN), Ministry of Agriculture (FJ), Ministry of Agriculture and Rural Affairs (CN)
Openalex Percentile: Top 44%
Catalytic C–H Functionalization Methods
DOISourceOpenAlex
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Direct allylic C(sp <sup>3</sup> )–H acylation of alkenes <i>via</i> metallaphotoredox catalysis using carboxylic acids · Green Chemistry (2025) | TGRS Research Map | TGRS