Doping-induced spin reorientation in kagome magnet <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>TmMn</mml:mi> <mml:mn>6</mml:mn> </mml:msub> <mml:msub> <mml:mi>Sn</mml:mi> <mml:mn>6</mml:mn> </mml:msub> </mm

The kagome-lattice compounds $R{\mathrm{Mn}}_{6}{\mathrm{Sn}}_{6}$ ($R$ is a rare-earth element), where the Mn atoms form a kagome net in the basal plane, are currently attracting a great deal of attention as they have been shown to host complex magnetic textures and electronic topological states strongly sensitive to the choice of the $R$ atom. Among the magnetic $R$ atoms, ${\mathrm{TmMn}}_{6}{\mathrm{Sn}}_{6}$ orders with the easy-plane magnetization forming a complex magnetic spiral along the $c$ axis. Previous neutron studies carried out on polycrystalline samples found that Ga doping changes the magnetic anisotropy from easy-plane to easy-axis. Here we present magnetic and magnetotransport measurements on a single crystal and first-principles calculations in the doping series of ${\mathrm{TmMn}}_{6}{\mathrm{Sn}}_{6\ensuremath{-}x}{\mathrm{Ga}}_{x}$. We find that the magnetic properties are highly sensitive even to a small concentration of Ga. With minimal Ga substitution, the easy-plane anisotropy is maintained, which gradually changes to the easy-axis anisotropy with increasing Ga. We discuss these observations with respect to the effect of Ga doping on magnetocrystalline anisotropy and Tm crystal field.

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Publication Details

Journal
Physical Review Materials
Published
2025-11-19
DOI
https://doi.org/10.1103/qbwt-qdt7
Primary Topic
Topological Materials and Phenomena
Type
article
Field-Weighted Citation Impact
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article

Doping-induced spin reorientation in kagome magnet <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>TmMn</mml:mi> <mml:mn>6</mml:mn> </mml:msub> <mml:msub> <mml:mi>Sn</mml:mi> <mml:mn>6</mml:mn> </mml:msub> </mm

Physical Review Materials
Topological Materials and Phenomena
article

Doping-induced spin reorientation in kagome magnet <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>TmMn</mml:mi> <mml:mn>6</mml:mn> </mml:msub> <mml:msub> <mml:mi>Sn</mml:mi> <mml:mn>6</mml:mn> </mml:msub> </mm

article en

Abstract

The kagome-lattice compounds $R{\mathrm{Mn}}_{6}{\mathrm{Sn}}_{6}$ ($R$ is a rare-earth element), where the Mn atoms form a kagome net in the basal plane, are currently attracting a great deal of attention as they have been shown to host complex magnetic textures and electronic topological states strongly sensitive to the choice of the $R$ atom. Among the magnetic $R$ atoms, ${\mathrm{TmMn}}_{6}{\mathrm{Sn}}_{6}$ orders with the easy-plane magnetization forming a complex magnetic spiral along the $c$ axis. Previous neutron studies carried out on polycrystalline samples found that Ga doping changes the magnetic anisotropy from easy-plane to easy-axis. Here we present magnetic and magnetotransport measurements on a single crystal and first-principles calculations in the doping series of ${\mathrm{TmMn}}_{6}{\mathrm{Sn}}_{6\ensuremath{-}x}{\mathrm{Ga}}_{x}$. We find that the magnetic properties are highly sensitive even to a small concentration of Ga. With minimal Ga substitution, the easy-plane anisotropy is maintained, which gradually changes to the easy-axis anisotropy with increasing Ga. We discuss these observations with respect to the effect of Ga doping on magnetocrystalline anisotropy and Tm crystal field.

Physical Review MaterialsVol. 9(11)
University of Notre Dame (US), Argonne National Laboratory (US), George Mason University (US), Ames National Laboratory (US), Urology of Virginia (US), University of Virginia (US), Rice University (US)
Openalex Percentile: Top 41%
Topological Materials and Phenomena
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