A unified mechanistic framework for DDQ-promoted transformation of electron-deficient alkenes: the addition-coupled electron transfer (ACET) perspective

High-level computations and experiments reveal that DDQ–alkene oxidations operate on an ACET–AdE2 continuum, providing the first experimental validation of ACET and redefining electron-transfer reactivity beyond the SET paradigm.

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Publication Details

Journal
Organic Chemistry Frontiers
Published
2025-11-13
DOI
https://doi.org/10.1039/d5qo01444a
Primary Topic
Radical Photochemical Reactions
Type
article
Field-Weighted Citation Impact
0.00
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article

A unified mechanistic framework for DDQ-promoted transformation of electron-deficient alkenes: the addition-coupled electron transfer (ACET) perspective

Organic Chemistry Frontiers
Radical Photochemical Reactions
article

A unified mechanistic framework for DDQ-promoted transformation of electron-deficient alkenes: the addition-coupled electron transfer (ACET) perspective

article en

Abstract

High-level computations and experiments reveal that DDQ–alkene oxidations operate on an ACET–AdE2 continuum, providing the first experimental validation of ACET and redefining electron-transfer reactivity beyond the SET paradigm.

Organic Chemistry FrontiersVol. 13(2)
Beijing Railway Institute of Mechanical & Electrical Engineering Group (China) (CN), The First People's Hospital of Xiaoshan District, Hangzhou (CN)
Openalex Percentile: Top 44%
Radical Photochemical Reactions
DOISourceOpenAlex
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A unified mechanistic framework for DDQ-promoted transformation of electron-deficient alkenes: the addition-coupled electron transfer (ACET) perspective · Organic Chemistry Frontiers (2025) | TGRS Research Map | TGRS