Organocatalytic enantioselective synthesis of tetrasubstituted chiral allenes <i>via</i> 1,12-addition of alkynyl aza-biphenyl quinone methides formed <i>in situ</i>

Chiral phosphoric acid catalyzed enantioselective synthesis of tetrasubstituted chiral allenes has been achieved via 1,12-addition of indole-2-carboxylates to alkynyl aza-biphenyl quinone methides formed in situ from α-functionalized alcohols.

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Publication Details

Journal
Organic Chemistry Frontiers
Published
2025-11-10
DOI
https://doi.org/10.1039/d5qo01403d
Citations
2
Primary Topic
Synthesis of Indole Derivatives
Type
article
Field-Weighted Citation Impact
1.87
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article

Organocatalytic enantioselective synthesis of tetrasubstituted chiral allenes via 1,12-addition of alkynyl aza-biphenyl quinone methides formed in situ

2 citations
Organic Chemistry Frontiers
Synthesis of Indole Derivatives
1.87
article

Organocatalytic enantioselective synthesis of tetrasubstituted chiral allenes via 1,12-addition of alkynyl aza-biphenyl quinone methides formed in situ

article en
2 citations

Abstract

Chiral phosphoric acid catalyzed enantioselective synthesis of tetrasubstituted chiral allenes has been achieved via 1,12-addition of indole-2-carboxylates to alkynyl aza-biphenyl quinone methides formed in situ from α-functionalized alcohols.

Organic Chemistry FrontiersVol. 13(2)
Qingdao University (CN), Southern University of Science and Technology (CN)
Openalex Percentile: Top 13%
Synthesis of Indole Derivatives
1.87
DOISourceOpenAlex
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Organocatalytic enantioselective synthesis of tetrasubstituted chiral allenes <i>via</i> 1,12-addition of alkynyl aza-biphenyl quinone methides formed <i>in situ</i> · Organic Chemistry Frontiers (2025) | TGRS Research Map | TGRS