Unveiling anionic migration mechanisms governed by mixed-anion chemistry in melilite oxyfluorides
Defect-level immobile fluorine was differentiated by combined experimental and theoretical 19 F solid-state NMR in melilite oxide host, unveiling the importance of homoanionic site exchange for anionic conduction in mixed anion compounds.
Institutions
- Centre National de la Recherche Scientifique (FR)
- Southern University of Science and Technology (CN)
- Guilin University of Technology (CN)
- China Spallation Neutron Source (CN)
- Conditions Extrêmes et Matériaux Haute Température et Irradiation (FR)
- University of Science and Technology Beijing (CN)
Publication Details
- Journal
- Inorganic Chemistry Frontiers
- Published
- 2025-11-05
- DOI
- https://doi.org/10.1039/d5qi01806d
- Primary Topic
- Inorganic Fluorides and Related Compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Natural Science Foundation of China